Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 2208-59-5, is researched, SMILESS is C1(C2=CC=NC=C2)=NC3=CC=CC=C3N1, Molecular C12H9N3Journal, Inorganica Chimica Acta called Unusual hexamers and infinite water chains trapped in the complexes of 2-(4-pyridyl)benzimidazole, Author is Xia, Chang-Kun; Lu, Can-Zhong; Wu, Xiao-Yuan; Chen, Li-Juan; Zhang, Quan-Zheng; Zhang, Jian-Jun; Wu, Ding-Ming, the main research direction is silver pyridylbenzimidazole complex water hexamer preparation structure; pyridylbenzimidazole terephthalate complex water trapped preparation structure; crystal structure pyridylbenzimidazole terephthalate silver complex water trapped.Reference of 2-(Pyridin-4-yl)-1H-benzo[d]imidazole.
Unusual hexamers and H2O chains were observed in the complexes of (HPyBIm)+•(Hterephate)-•(PyBIm)·4H2O (1) and [Ag2(PyBIm)2(μ2-SO4)]·4H2O (2), resp. (PyBIm = 2-(4-pyridyl)benzimidazole). In 1, a chair-shaped hexamer (not H2O hexamer) formed by the H2O mols. and carboxylate groups as well as 1-dimensional H2O chain are being observed While in 2, a H2O hexamer-shaped as parallelogram was obtained; more interestingly, the parallelogram-shaped H2O hexamers are further aggregated into tape like infinite H2O chain via H-bonding interactions.
Here is a brief introduction to this compound(2208-59-5)Reference of 2-(Pyridin-4-yl)-1H-benzo[d]imidazole, if you want to know about other compounds related to this compound(2208-59-5), you can read my other articles.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles