Extracurricular laboratory: Synthetic route of C7H8O

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Product Details of 100-51-6. I found the field of Polymer Science very interesting. Saw the article Mechanistic Insight into the Ring-Opening Polymerization of epsilon-Caprolactone and L-Lactide Using Ketiminate-Ligated Aluminum Catalysts published in 2019.0, Reprint Addresses Lin, YF (corresponding author), Kaohsiung Med Univ, Dept Fragrance & Cosmet Sci, Kaohsiung 80708, Taiwan.; Lin, YF (corresponding author), Kaohsiung Med Univ, Dept Med & Appl Chem, Kaohsiung 80708, Taiwan.. The CAS is 100-51-6. Through research, I have a further understanding and discovery of Benzyl Alcohol.

The reactivity and the reaction conditions of the ring-opening polymerization of epsilon-caprolactone (epsilon-CL) and L-lactide (LA) initiated by aluminum ketiminate complexes have been shown differently. Herein, we account for the observation by studying the mechanisms on the basis of density functional theory (DFT) calculations. The calculations show that the ring-opening polymerization of epsilon-CL and LA are rate-determined by the benzoxide insertion and the C-O bond cleavage step, respectively. Theoretical computations suggest that the reaction temperature of L-LA polymerization should be higher than that of epsilon-CL one, in agreement with the experimental data. To provide a reasonable interpretation of the experimental results and to give an insight into the catalyst design, the influence of the electronic, steric, and thermal effects on the polymerization behaviors will be also discussed in this study.

About Benzyl Alcohol, If you have any questions, you can contact Lin, YF; Jheng, NY or concate me.. Product Details of 100-51-6

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles