Ishihara, H; Huang, JH; Mochizuki, T; Hatano, M; Ishihara, K in [Ishihara, Hideyuki; Huang, Jianhao; Mochizuki, Takuya; Ishihara, Kazuaki] Nagoya Univ, Grad Sch Engn, Nagoya, Aichi 4648603, Japan; [Hatano, Manabu] Kobe Pharmaceut Univ, Grad Sch Pharmaceut Sci, Kobe, Hyogo 6588558, Japan published Enantio- and Diastereoselective Carbonyl-Ene Cyclization-Acetalization Tandem Reaction Catalyzed by Tris(pentafluorophenyl)borane-Assisted Chiral Phosphoric Acids in 2021.0, Cited 65.0. Name: 4-Methoxybenzaldehyde. The Name is 4-Methoxybenzaldehyde. Through research, I have a further understanding and discovery of 123-11-5.
Highly enantio- and diastereoselective carbonyl-ene cyclization was developed with the use of chiral Lewis acid-assisted chiral Bronsted acid (LBA) catalysts, which were prepared in situ from both sterically demanding tris(pentafluorophenyl)borane and chiral phosphoric acids. Along with the performance of standard carbonyl-ene cyclizations, carbonyl-ene cyclization-acetalization tandem reactions with the use of additional aldehydes were demonstrated with high enantio- and diastereoselectivities. On the basis of mechanistic examinations, a stepwise reaction pathway via tertiary carbocation intermediates involving possible transition states is proposed.
Welcome to talk about 123-11-5, If you have any questions, you can contact Ishihara, H; Huang, JH; Mochizuki, T; Hatano, M; Ishihara, K or send Email.. Name: 4-Methoxybenzaldehyde
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles