In 2020 ACS OMEGA published article about BENZYNE-CLICK CHEMISTRY; FACILE N-ARYLATION; O-ARYLATION; NUCLEOPHILIC-SUBSTITUTION; SELECTIVE SYNTHESIS; GENERATION; EFFICIENT; PHENOLS; MAGNESIUM; REAGENTS in [Muraca, Ana Carolina A.; Raminelli, Cristiano] Univ Fed Sao Paulo, Inst Ciencias Ambientais Quim & Farmaceut, BR-09972270 Diadema, Brazil in 2020, Cited 107. The Name is m-Methoxyphenol. Through research, I have a further understanding and discovery of 150-19-6. Computed Properties of C7H8O2
A class of aryne precursors, that is, 2-(trimethylsilyl)aryl 4-chlorobenzenesulfonates, has been developed through well-established synthetic routes, which allow the formation of arynes under relatively mild conditions. All the aryne precursors were obtained from phenols and 4-chlorobenzenesulfonyl chloride, an inexpensive and easy-to-handle reagent with relatively low toxicity, and subjected to nucleophilic addition reactions, providing addition products in yields of 24 to 92%, and to cycloaddition reactions, affording cycloadducts in yields up to 80%. This work provides interesting insights into the mechanisms of aryne generation. In addition, 2-(trimethylsilyl)phenyl 4-chlorobenzenesulfonate was successfully employed in the total synthesis of (+/-)-aporphine.
Computed Properties of C7H8O2. About m-Methoxyphenol, If you have any questions, you can contact Muraca, ACA; Raminelli, C or concate me.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles