Esgulian, M; Buchotte, M; Guillot, R; Deloisy, S; Aitken, DJ in [Esgulian, Mathieu; Buchotte, Marie; Guillot, Regis; Deloisy, Sandrine; Aitken, David J.] Univ Paris Saclay, Univ Paris Sud, CNRS, ICMMO,CP3A Organ Synth Grp & Serv Communs, 15 Rue Georges Clemenceau, F-91405 Orsay, France published Reversal of Diastereoselectivity in a Masked Acyl Cyanide (MAC) Reaction: Synthesis of Protected erythro-beta-Hydroxyaspartate Derivatives in 2019.0, Cited 70.0. Safety of Benzyl Alcohol. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6.
Using Garner’s aldehyde as a substrate, one-pot MAC hydroxyhomologation reactions proceeded in good yields and with anti selectivity for the first time (dr up to 9:1). The products were used to prepare a panel of protected derivatives of erythro-beta-hydroxyaspartic acid and erythro-beta-hydroxyasparagine as single enantiomers in a few steps.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles