An article Enantioselective Hydrogenations of Esters with Dynamic Kinetic Resolution WOS:000474812400032 published article about HOMOGENEOUS CATALYTIC-HYDROGENATION; CARBOXYLIC-ACID ESTERS; ASYMMETRIC HYDROGENATION; EFFICIENT HYDROGENATION; BIFUNCTIONAL ADDITION; RUTHENIUM COMPLEXES; ALCOHOLS; AMIDES; KETONES; BASE in [Endean, Riley T.; Rasu, Loorthuraja; Bergens, Steven H.] Univ Alberta, Dept Chem, Edmonton, AB T6G 2G2, Canada in 2019.0, Cited 54.0. Formula: C7H8O2. The Name is m-Methoxyphenol. Through research, I have a further understanding and discovery of 150-19-6
The catalyst system trans-Ru(H)(2)(1R,2R)-N,N-bis{2-[bis (3,-dimethylphenyl)phosphino]benzyl}cyclohexane-1,2-diamine, NaOEt, in DME or THF solvent hydrogenates a series of functionalized racemic esters under mild conditions with dynamic kinetic resolution with up to 100% conversion, 95% enantiomeric excess, and 1000 turnovers. A preliminary mechanistic study reveals that several exchange and scrambling processes occur during the hydrogenation.
Welcome to talk about 150-19-6, If you have any questions, you can contact Endean, RT; Rasu, L; Bergens, SH or send Email.. Formula: C7H8O2
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles