An article Pseudo-Five-Component Stereoselective Synthesis of Highly Functionalized 3-Azabicyclo[3.3.1]nona-2,7-dienes WOS:000662914800002 published article about ONE-POT; MULTICOMPONENT REACTIONS; MALONONITRILE DIMER; ACTIVATED NITRILES; DERIVATIVES; CHEMISTRY; REARRANGEMENT; ANTIOXIDANT; REACTIVITY; INHIBITORS in [Ismiyev, A. I.; Magarramov, A. M.] Baku State Univ, AZ-1148 Baku, Azerbaijan; [Dotsenko, V. V.] Kuban State Univ, Krasnodar 350040, Russia; [Dotsenko, V. V.; Aksenov, N. A.; Aksenova, I., V] North Caucasus Fed Univ, Stavropol 355009, Russia in 2021, Cited 66. HPLC of Formula: C8H8O2. The Name is 4-Methoxybenzaldehyde. Through research, I have a further understanding and discovery of 123-11-5
The reaction of aromatic aldehydes with malononitrile, ethyl or butyl cyanoacetate and acetylacetone in the presence of NaOH under mild conditions (EtOH, 25 degrees C) led to the formation of new series of (1S,5R,6R,9R)/(1R,5S,6S,9S)-2-amino-6,9-diaryl-7-acetyl-8-methyl-4-oxo-5-cyano-3-azabicyclo[3.3.1]nona-2,7-diene-1-carboxylic acids esters. A plausible mechanism of the cascade reaction was proposed.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles