In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called Cobalt-catalyzed intramolecular decarbonylative coupling of acylindoles and diarylketones through the cleavage of C-C bonds, published in 2020, which mentions a compound: 1008-89-5, mainly applied to indole preparation; acyl indole intramol decarbonylative coupling cobalt catalyzed; aryl pyridine preparation; diaryl ketone intramol decarbonylative coupling cobalt catalyzed, Synthetic Route of C11H9N.
A cobalt-N-heterocyclic carbene catalytic systems for the intramol. decarbonylative coupling through the chelation-assisted C-C bond cleavage of acylindoles and diarylketones was reported. The reaction tolerated a wide range of functional groups such as alkyl, aryl and heteroaryl groups, giving the decarbonylative products in moderate to excellent yields. This transformation involved the cleavage of two C-C bonds and formation of a new C-C bond without the use of noble metals, thus reinforcing the potential application of decarbonylation as an effective tool for C-C bond formation.
The article 《Cobalt-catalyzed intramolecular decarbonylative coupling of acylindoles and diarylketones through the cleavage of C-C bonds》 also mentions many details about this compound(1008-89-5)Synthetic Route of C11H9N, you can pay attention to it or contacet with the author([email protected]; [email protected]; [email protected]; [email protected]) to get more information.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles