Name: 4-Methoxybenzaldehyde. Recently I am researching about METAL-ORGANIC FRAMEWORK; ACID-BASE CATALYST; ANTI-AIDS AGENTS; CRYSTAL-STRUCTURES; DCP ANALOGS; COORDINATION; AMINE; DIHYDROPYRIMIDINES; LIGANDS, Saw an article supported by the UGC-BSR [F.18-1/2011(BSR)]; UGC-BSR Research Start-Up Grant [F.30-431/2018(BSR)]; Banaras Hindu University-Seed Grant under IoE scheme; CSIR-SRF fellowshipCouncil of Scientific & Industrial Research (CSIR) – India; Department of Chemistry, Institute of Science, Banaras Hindu University; UGC CAS-II; EPSRC (U.K.)UK Research & Innovation (UKRI)Engineering & Physical Sciences Research Council (EPSRC); University of Reading. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Anamika; Yadav, CL; Drew, MGB; Kumar, K; Singh, N. The CAS is 123-11-5. Through research, I have a further understanding and discovery of 4-Methoxybenzaldehyde
Four new mononuclear/coordination polymeric (CP) zinc(II) complexes (1-4) of ferrocenyl/pyridyl-functionalized dithiocarbamate ligands, N-ferrocenylmethyl-N-butyl dithiocarbamate (L1), N-ferrocenylmethyl-N-ethylmorpholine dithiocarbamate (L2), N-ferrocenylmethyl-N-2-(diethylamino)ethylamine dithiocarbamate (L3), and N-4-methoxybenzyl-N-3-methylpyridyl dithiocarbamate (L4), have been synthesized and characterized by elemental analyses, IR, UV-vis, and H-1 and C-13{H-1} NMR spectroscopic techniques. The solid-state structures of complexes 1, 3, and 4 have been determined by single-crystal X-ray crystallography as well as powder X-ray diffraction. Single-crystal X-ray crystallography revealed a monomeric structure for complex 1 but 1D polymeric structures for complexes 3 and 4. In all complexes, dithiocarbamate ligands are bonded to the Zn(II) metal ion in a S<^>S chelating mode, and in the CPs, N atoms on the 2-(diethylamino)ethylamine and 3-pyridyl functionalities in the ligands on the neighboring molecules are also bonded to metal centers, leading to the formation of either a discrete tetrahedral molecule in 1 or 1D CP structures in 3 and 4. The Zn(II) metal centers in the polymeric structures exhibited either square-pyramidal or octahedral geometries. The supramolecular structures in these complexes are sustained via C-H center dot center dot center dot pi (ZnCS2, chelate; 3 and 4), C-H center dot center dot center dot pi, and H center dot center dot center dot H interactions. The catalytic performances of complexes have also been assessed in the Knoevenagel condensation and one-pot multicomponent reactions. Catalysis results showed that the CP 3 acts as a heterogeneous bifunctional catalyst with excellent transformation efficiency at low catalyst loading.
Name: 4-Methoxybenzaldehyde. Bye, fridends, I hope you can learn more about C8H8O2, If you have any questions, you can browse other blog as well. See you lster.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles