Recently I am researching about TRANSITION-METAL-FREE; ASYMMETRIC-SYNTHESIS; ENANTIOSELECTIVE CONSTRUCTION; FLUORINATED ALCOHOLS; CROSS-COUPLINGS; CYCLOADDITION REACTIONS; PRIVILEGED STRUCTURES; NAZAROV CYCLIZATION; QUATERNARY CENTER; NATURAL-PRODUCTS, Saw an article supported by the . Product Details of 150-19-6. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Aota, Y; Doko, Y; Kano, T; Maruoka, K. The CAS is 150-19-6. Through research, I have a further understanding and discovery of m-Methoxyphenol
Nucleophilic addition to the oxy-allyl cation intermediate has emerged as a promising methodology for functionalization of the alpha-position of carbonyl compounds in an umpolung fashion. However, a structure of available carbon nucleophiles to trap the catalytically generated oxy-allyl cation has been limited to highly nucleophilic ones. Herein, we report the Bronsted acid-catalyzed alpha-arylation of ketones employing less explored phenolic nucleophiles as carbon nucleophiles in the oxy-allyl cation catalysis, affording ketones bearing an all carbon quaternary center at the alpha-position.
About m-Methoxyphenol, If you have any questions, you can contact Aota, Y; Doko, Y; Kano, T; Maruoka, K or concate me.. Product Details of 150-19-6
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles