Application In Synthesis of Benzyl Alcohol. I found the field of Chemistry very interesting. Saw the article Micropores Induced Stereoselective Synthesis of E-imines: Synergistic Effect between Cerium Species and Micropores in CeAlPO-5 Molecular Sieves published in 2019.0, Reprint Addresses Ke, QP (corresponding author), Anhui Univ Technol, Coll Chem & Chem Engn, Maanshan 243002, Anhui, Peoples R China.. The CAS is 100-51-6. Through research, I have a further understanding and discovery of Benzyl Alcohol.
Metal-doped zeolitic microporous materials are often viewed as something extremely negative as catalysis for the reactions involving aromatic molecules because of severe diffusion limitation. For these reasons, many chemists aim to development of the large microporous or hierarchical micro-mesoporous zeolites as supports that allow for the access of the bulky reactants. But the small micropore with respect to an aromatic molecules-involving reaction is not always a negative point. Here we employed a hierarchical micro-mesoporous CeAlPO-5 molecular sieve (HP-CeAlPO-5) as the catalyst that can catalyze stereoselective synthesis of E-imines through the reaction of alcohols with amines. Control reactions, DFT calculations and GC-MS analyses demonstrated that the feature of the uniform small micropore in the HP-CeAlPO-5 catalyst play a key role in the stereoselective synthesis of E-imines. In addition, the reaction tolerates a broad range of alcohols and amines, and can be performed with as little as 0.89 mole percent catalyst in more than 90.6 percent yield and about 99.7 : 0.3 stereoselective ratio. This zeolitic catalyst provides a conceptually new and practical protocol to stereoselective synthesis of E-imine compounds.
Application In Synthesis of Benzyl Alcohol. Welcome to talk about 100-51-6, If you have any questions, you can contact Jin, YX; Cao, YL; Fang, GY; Ruan, F; Ke, QP or send Email.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles