Authors Cervi, A; Vo, Y; Chai, CLL; Banwell, MG; Lan, P; Willis, AC in AMER CHEMICAL SOC published article about SOLID-PHASE SYNTHESIS; CATALYZED HYDROARYLATION; CONVENIENT SYNTHESIS; RING-CLOSURE; EFFICIENT; ACID; CYCLIZATION; ANALOGS; MILD; ALKENYLATION in [Cervi, Aymeric; Vo, Yen; Banwell, Martin G.; Willis, Anthony C.] Australian Natl Univ, Res Sch Chem, Inst Adv Studies, Canberra, ACT 2601, Australia; [Cervi, Aymeric; Chai, Christina L. L.] Inst Chem & Engn Sci, Singapore 138665, Singapore; [Chai, Christina L. L.] Natl Univ Singapore, Dept Pharm, Singapore 117543, Singapore; [Banwell, Martin G.; Lan, Ping] Jinan Univ, Inst Adv & Appl Chem Synth, Guangzhou 510632, Guangdong, Peoples R China in 2021, Cited 99. Application In Synthesis of Mequinol. The Name is Mequinol. Through research, I have a further understanding and discovery of 150-76-5
Methods are reported for the efficient assembly of a series of phenol-derived propiolates, including the parent system 56, and their Au(I)-catalyzed cyclization (intramolecular hydroarylation) to give the corresponding coumarins (e.g., 1). Simple syntheses of natural products such as ayapin (144) and scoparone (145) have been realized by such means, and the first of these subject to single-crystal X-ray analysis. A related process is described for the conversion of propargyl ethers such as 156 into the isomeric 2H-chromene precocene I (159), a naturally occurring inhibitor of juvenile hormone biosynthesis.
Application In Synthesis of Mequinol. About Mequinol, If you have any questions, you can contact Cervi, A; Vo, Y; Chai, CLL; Banwell, MG; Lan, P; Willis, AC or concate me.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles