On October 31, 2002, Nowak, Ireneusz; George, Clifford published an article.Quality Control of H-Idc-OH The title of the article was Stereoselective dimerization of benzylic amines derived from indoline. And the article contained the following:
Treatment of benzylic amines derived from 2-(acyloxymethyl)-5-nitroindolines with sodium hexamethyldisilazide leads to dimeric products resulting from deprotonation in the benzylic position, oxidation of the resulting carbanion to radical by the nitroarene moiety of another mol., and stereoselective radical recombination. Only those two of six possible diastereoisomers are formed in which the recombination takes place from the less hindered face in the more stable conformation of the presumably near-planar radical. The experimental process involved the reaction of H-Idc-OH(cas: 79815-20-6).Quality Control of H-Idc-OH
The Article related to stereoselective dimerization benzylic amine indoline derivative, crystal structure bishalophenylethanediylbisindolemethanol preparation, mol structure bishalophenylethanediylbisindolemethanol preparation, radical dimerization stereochem benzylindollemethanol ester preparation and other aspects.Quality Control of H-Idc-OH
Referemce:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles