An article Nickel- and Palladium-Catalyzed Cross-Coupling of Aryl Fluorosulfonates and Phosphites: Synthesis of Aryl Phosphonates WOS:000609907500001 published article about SULFURYL FLUORIDE; BOND FORMATION; PHENOLS; ACIDS; ESTERS; SUFEX in [Zhang, Guofu; Wang, Jing; Guan, Chenfei; Ding, Chengrong] Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310014, Peoples R China; [Zhao, Yiyong] Zhejiang Ecol Environm Low Carbon Dev Ctr, Hangzhou 310012, Peoples R China in 2021, Cited 34. COA of Formula: C8H8O2. The Name is 4′-Hydroxyacetophenone. Through research, I have a further understanding and discovery of 99-93-4
The synthesis of aryl phosphonates via nickel and palladium-catalyzed cross-coupling of aryl fluorosulfonates and phosphites is described. The products were obtained in good to excellent yields under mild conditions with broad functional group compatibility, employing either Pd(OAc)(2) and DPEPhos or the readily available NiCl2(dme) and Xantphos as catalytic systems. Noteworthily, the present C(sp(2))-P bond formation method could be applied to the direct conversion of phenols to the corresponding aryl phosphonates in one pot via reaction of phenols with SO2F2 and subsequent palladium-catalyzed cross-coupling.
COA of Formula: C8H8O2. About 4′-Hydroxyacetophenone, If you have any questions, you can contact Zhang, GF; Wang, J; Guan, CF; Zhao, YY; Ding, CR or concate me.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles