An article Efficient and selective oxidation of alcohols to carbonyl compounds at room temperature by a ruthenium complex catalyst and hydrogen peroxide WOS:000507310600049 published article about IRON-OXO COMPLEXES; HIGHLY EFFICIENT; SECONDARY ALCOHOLS; BENZYL ALCOHOL; IONIC LIQUID; SOLVENT-FREE; AEROBIC OXIDATION; WATER; EPOXIDATION; PORPHYRIN in [Wang, Jie-Xiang; Ji, Hong-Bing] Guangdong Univ Petrochem Technol, Sch Chem Engn, Maoming 515000, Peoples R China; [Zhou, Xian-Tai; Han, Qi; Guo, Xiao-Xuan; Liu, Xiao-Hui; Xue, Can] Sun Yat Sen Univ, Sch Chem Engn & Technol, Zhuhai 519082, Peoples R China; [Ji, Hong-Bing] Sun Yat Sen Univ, Fine Chem Ind Res Inst, Sch Chem, Key Lab Low Carbon Chem & Energy Conservat Guangd, Guangzhou 510275, Peoples R China in 2019.0, Cited 55.0. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6. Product Details of 100-51-6
In this study, convenient and selective oxidation of alcohols using aqueous hydrogen peroxide to yield carbonyl compounds was studied. Using the ruthenium-(4-methylphenyl-2,6-bispydinyl) pyridinedicarboxylate complex [Ru(mpbp)(pydic)] as a catalyst, primary and secondary alcohols were oxidized to aldehydes and ketones at room temperature with a satisfactory yield and excellent selectivity. The influence of various reaction parameters, such as solvent, catalyst and oxidant amount on both the activity and selectivity was also evaluated. Kinetic studies showed that the oxidation of alcohol was first order in terms of the substrate and hydrogen peroxide, and was second order in terms of the catalyst. A plausible mechanism involving ruthenium-oxo species with electrophilic character was proposed based on the in situ UV-vis spectroscopy studies and Hammett plots.
Product Details of 100-51-6. About Benzyl Alcohol, If you have any questions, you can contact Wang, JX; Zhou, XT; Han, Q; Guo, XX; Liu, XH; Xue, C; Ji, HB or concate me.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles