An article Remodeling of N-Heterocyclic Iminato Ligand Frameworks for the Facile Synthesis of Isoureas from Alcohols and Carbodiimides Promoted by Organoactinide (Th, U) Complexes WOS:000661452700074 published article about CATALYTIC ADDITION; INTERMOLECULAR ADDITION; METAL; CHEMISTRY; DERIVATIVES; GUANIDINES; BONDS; ALKYL in [Makarov, Konstantin; Saha, Sayantani; Ghatak, Tapas; Fridman, Natalia; Eisen, Moris S.] Technion Israel Inst Technol, Schulich Fac Chem, IL-3200008 Technion, Israel in 2021.0, Cited 44.0. Recommanded Product: Mequinol. The Name is Mequinol. Through research, I have a further understanding and discovery of 150-76-5
A new class of actinide complexes [(L)An(N{SiMe3}(2))(3)] (An = Th or U) (Th1-Th3 and U1-U3) supported by highly nucleophilic seven-membered N-heterocyclic iminato ligands were synthesized and fully characterized by single-crystal X-ray diffraction. These complexes were successfully exploited as powerful catalysts for the addition of alcohols to carbodiimides to yield the corresponding desirable isourea products at room temperature with short reaction times and excellent yields. Thorough stoichiometric, thermodynamic, and kinetic studies were carried out, allowing us to propose a plausible mechanism for the catalytic reaction.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles