An article Development of a new bicyclic imidazole nucleophilic organocatalyst for direct enantioselective C-acylation WOS:000501342100008 published article about DYNAMIC KINETIC RESOLUTION; ALPHA,BETA-UNSATURATED ACYL CHLORIDES; ASYMMETRIC CATALYSIS; SILYL PROTECTION; ALCOHOLS; DESYMMETRIZATION; DERIVATIVES; AMINATION; DESIGN; ESTERS in [Zhou, Muxing; He, Ende; Zhang, Lu; Zhang, Zhenfeng; Liu, Yangang; Zhang, Wanbin] Shanghai Jiao Tong Univ, Shanghai Key Lab Mol Engn Chiral Drugs, Sch Pharm, 800 Dongchuan Rd, Shanghai 200240, Peoples R China; [Chen, Jianzhong; Zhang, Wanbin] Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, 800 Dongchuan Rd, Shanghai 200240, Peoples R China in 2019, Cited 62. The Name is m-Methoxyphenol. Through research, I have a further understanding and discovery of 150-19-6. Recommanded Product: 150-19-6
A novel chiral nucleophilic organocatalyst easily synthesized from simple starting materials bearing a 5,6,7,8-tetrahydroimidazo[1,2-a]pyridine skeleton has been developed and successfully applied in the direct enantioselective C-acylation of 3-substituted benzofuranones. Its catalytic efficiency was shown to be comparable to that of the previously reported chiral 6,7-dihydro-5H-pyrrolo[1,2-a]imidazole catalyst. A wide range of 3,3-disubstituted benzofuranones, possessing a quaternary stereocenter, were synthesized with high yields and enantioselectivities.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles