Palladium Catalyzed Aryl(alkyl)thiolation of Unactivated Arenes was written by Saravanan, Perumal;Anbarasan, Pazhamalai. And the article was included in Organic Letters in 2014.Synthetic Route of C14H9NO2S This article mentions the following:
A general palladium-catalyzed aryl(alkyl)thiolation of various substituted unactivated arenes is accomplished for the synthesis of diverse unsym. diaryl(alkyl) sulfides in good yield employing electrophilic sulfur reagents derived from succinimide. E.g., in presence of Pd(OAc)2 in TFA, arylthiolation of mesitylene with 1-(phenylthio)pyrrolidine-2,5-dione (I) gave 95% sulfide II. The developed strategy was coupled with intramol. arylation of a C-H bond to afford dibenzothiphene derivatives, an important moiety in material science as organic semiconductors. In the experiment, the researchers used many compounds, for example, 2-(Phenylthio)isoindoline-1,3-dione (cas: 14204-27-4Synthetic Route of C14H9NO2S).
2-(Phenylthio)isoindoline-1,3-dione (cas: 14204-27-4) belongs to indole derivatives. Indole exists overwhelmingly in the 1H-indole form as do other simple indoles. Due to this activity, the indole ring system has become an important component or intermediate in the synthesis of heterocycles.Synthetic Route of C14H9NO2S
Referemce:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles