An article Regioselective Ring-Opening of Glycidol to Monoalkyl Glyceryl Ethers Promoted by an [OSSO]-Fe-III Triflate Complex WOS:000476079000001 published article about VALUE-ADDED PRODUCT; 2,3-EPOXY ALCOHOLS; ORGANIC-SYNTHESIS; IRON CATALYSIS; CARBON-DIOXIDE; SUBSTRATE; EFFICIENT; EPOXIDES; METAL; TRANSFORMATION in [Della Monica, Francesco; Ricciardi, Maria; Proto, Antonio; Cucciniello, Raffaele; Capacchione, Carmine] Univ Salerno, Dipartimento Chim & Biol Adolfo Zambelli, Via Giovanni Paolo II, I-13284084 Salerno, SA, Italy in 2019.0, Cited 45.0. Formula: C7H8O. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6
A Fe-III-triflate complex, bearing a bis-thioether-di-phenolate [OSSO]-type ligand, was discovered to promote the ring-opening of glycidol with alcohols under mild reaction conditions (0.05 mol % catalyst and 80 degrees C). The reaction proceeded with high activity (initial turnover frequency of 1680 h(-1) for EtOH) and selectivity (>95 %) toward the formation of twelve monoalkyl glyceryl ethers (MAGEs) in a regioselective fashion (84-96 % yield of the non-symmetric regioisomer). This synthetic approach allows the conversion of a glycerol-derived platform molecule (i.e., glycidol) to high-value-added products by using an Earth-crust abundant metal-based catalyst.
About Benzyl Alcohol, If you have any questions, you can contact Della Monica, F; Ricciardi, M; Proto, A; Cucciniello, R; Capacchione, C or concate me.. Formula: C7H8O
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles