Recently I am researching about CATIONIC-POLYMERIZATION; EFFICIENT SYNTHESIS; CHEMISTRY; SILYLKETENES; POLYMERS, Saw an article supported by the National Science FoundationNational Science Foundation (NSF) [NSF 1807510]; NSFNational Science Foundation (NSF) [MRI-1334048]. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Mitchell, SM; Xiang, Y; Matthews, R; Arnburgey, AM; Pentzer, EB. The CAS is 150-19-6. Through research, I have a further understanding and discovery of m-Methoxyphenol. Product Details of 150-19-6
Silyl-substituted ketenes are attractive molecular building blocks due to their stability and ease of storage, as opposed to unstable alkyl and aryl ketenes. To better understand the reactivity of silyl ketenes and, in turn, their use in the preparation of highly functionalized small molecules, the reaction of silyl ketenes with different nucleophiles was studied. The addition of alcohol, amine, or thiol nucleophiles to the central carbon of silyl ketene, followed by proton transfer afforded alpha-silyl ester, amide, or thio-ester, respectively. Catalytic amounts of Lewis acid greatly increase the rate of the reaction, and the impact of nucleophile, Lewis acid, and silyl substituent are evaluated. The small molecules produced from these reactions give insight into the use of silyl ketenes as building blocks for complex molecular structures.
About m-Methoxyphenol, If you have any questions, you can contact Mitchell, SM; Xiang, Y; Matthews, R; Arnburgey, AM; Pentzer, EB or concate me.. Product Details of 150-19-6
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles