An article Catalytic oxidation of alcohols using Fe-bTAML and NaClO: Comparing the reactivity of Fe(V)O and Fe(IV)O intermediates WOS:000454151300059 published article about H BOND OXIDATION; C-H; AEROBIC OXIDATION; SECONDARY ALCOHOLS; HYDROGEN-PEROXIDE; IRON COMPLEXES; MECHANISM; FE-V(O); NANOPARTICLES; ACTIVATION in [Jana, Sandipan; Thomas, Jithin; Sen Gupta, Sayam] IISER, Dept Chem Sci, Kolkata 741246, Mohanpur, India in 2019.0, Cited 64.0. Computed Properties of C7H8O. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6
We demonstrate the selective oxidation of secondary alcohols and activated primary alcohols to their corresponding aldehydes or ketones using Fe-bTAML as the catalyst and sodium hypochlorite (NaClO) as the oxidant. Good to excellent yields of 80%-99% for the carbonyl compounds and turnover numbers up to similar to 500 was obtained with this catalytic system. The reactions are clean, performed under mild conditions (air, room temperature) and yielded sodium chloride as the only by-product. The yield and turnover number were dependent on the pH of the reaction and this difference was attributed to the different reactive intermediates that was formed at pH 7 and pH 12 (Fe-V(O) and Fe-IV(O) respectively). Reactions involving the Fe-V(O) intermediate oxidize secondary alcohols more efficiently than its Fe-IV(O) analog. This trend was reversed for the oxidation of activated primary alcohols where reactions involving Fe-IV(O) afforded much higher TON’s. This reactivity trend can be explained from the differences in bond dissociation energy (BDE) of their corresponding one electron reduced species ([Fe-IV-OH], similar to 99 kcal/mol; [Fe-III-OH], similar to 83 kcal/mol) as well as their relative stabilities in the solvent during reaction. This catalytic system was found to be unsuitable for nonconjugated primary alcohol due to the formation of the inactive Fe-IV(OMe) intermediate after one catalytic cycle.
Computed Properties of C7H8O. About Benzyl Alcohol, If you have any questions, you can contact Jana, S; Thomas, J; Sen Gupta, S or concate me.
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Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles