Computed Properties of C12H9N3. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: 2-(Pyridin-4-yl)-1H-benzo[d]imidazole, is researched, Molecular C12H9N3, CAS is 2208-59-5, about Syntheses and crystal structures of four silver(I) complexes based on 2-(4-pyridyl)benzimidazole.
Four new Ag(I) complexes constructed with 2-(4-pyridyl)benzimidazole, namely, [Ag(PyBIm)(H2O)]·NO3 (1), [Ag(PyBIm)(H2O)]·ClO4 (2), [Ag2(PyBIm)2](SiF6)·2H2O (3) and [Ag(PyBIm)(HBDC)] (4) (PyBIm = 2-(4-pyridyl)benzimidazole, BDC = 1,3-benzenedicarboxylate) were synthesized and characterized by x-ray crystallog. All the Ag(I) atoms in complexes 1-4 are bridged by the different PyBIm ligands via NPy and NBIm into 1-dimensional zigzag chains. The anions do not coordinate to the Ag(I) atoms and only act as counterions in complexes 1-3. Due to the anions, different H bonding systems are found in those three compounds, resulting in the different crystal packing. Through H bonding interactions, the structures of complexes 1-3 display a double layer, a three-dimensional framework and a novel double chain, resp. In complex 4, the HBDC- anions act not only as a counterion, but also as bridging ligands, which lead the zigzag [Ag2(PyBIm)2]∞ chain into a two-dimensional undulating sheet. The sheets are connected through H-bonding as well as π-π interactions into a three-dimensional framework. The thermal stabilities of the four complexes and anion exchange properties of complexes 2 and 3 were also studied.
Although many compounds look similar to this compound(2208-59-5)Computed Properties of C12H9N3, numerous studies have shown that this compound(SMILES:C1(C2=CC=NC=C2)=NC3=CC=CC=C3N1), has unique advantages. If you want to know more about similar compounds, you can read my other articles.
Reference:
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