Tag: 100-200

On December 8, 2010, Lin, Ning; Chen, Miao-Miao; Luo, Ren-Shi; Deng, Yan-Qiu; Lu, Gui published an article.Safety of H-Idc-OH The title of the article was Indolinylmethanol catalyzed enantioselective Reformatsky reaction with ketones. And the article contained the following:

A series of chiral indolinylmethanol ligands have been applied for the first time in the asym. Reformatsky reaction of an α-bromoester with ketones. In the presence of NiBr2 and zinc powder, up to 75% yield and 87% ee were obtained for a variety of aromatic and aliphatic ketones. The use of Ni(acac)2 resulted in 96% ee although the corresponding yield was low. This process provided a convenient method to access synthetically useful chiral β-hydroxyesters. The experimental process involved the reaction of H-Idc-OH(cas: 79815-20-6).Safety of H-Idc-OH

The Article related to hydroxy ester asym synthesis, asym reformatsky reaction bromo ester ketone nickel indolinylmethanol catalyst, General Organic Chemistry: Synthetic Methods and other aspects.Safety of H-Idc-OH

Referemce:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

On August 7, 2015, Chen, Tao; Foo, Thomas Jian Yao; Yeung, Ying-Yeung published an article.Reference of Methyl 2-methyl-1H-indole-3-carboxylate The title of the article was Indole-Catalyzed Bromolactonization in Lipophilic Solvent: A Solid-Liquid Phase Transfer Approach. And the article contained the following:

We have developed a novel indole-catalyzed bromolactonization of olefinic acids. The reaction could be conducted in lipophilic solvent through a solid-liquid phase transfer mechanism. This catalytic protocol has been applied to the synthesis of base-sensitive bromolactones. The experimental process involved the reaction of Methyl 2-methyl-1H-indole-3-carboxylate(cas: 65417-22-3).Reference of Methyl 2-methyl-1H-indole-3-carboxylate

The Article related to olefinic acid indole bromolactonization catalyst solid liquid phase transfer, bromolactone preparation, General Organic Chemistry: Synthetic Methods and other aspects.Reference of Methyl 2-methyl-1H-indole-3-carboxylate

Referemce:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

On April 5, 2019, Shi, Yao; Wong, Jonathan; Ke, Zhihai; Yeung, Ying-Yeung published an article.SDS of cas: 65417-22-3 The title of the article was Lipophilic Indole-Catalyzed Intermolecular Bromoesterification of Olefins in Nonpolar Media. And the article contained the following:

An environmentally benign and highly versatile catalytic protocol has been successfully applied in the intermol. bromoesterification between various olefins and carboxylic acids. The use of a highly lipophilic indole catalyst and 1,3-dibromo-5,5-dimethylhydantoin (DBDMH) as the bromine source allows the reaction to proceed in heptane via a solid-liquid phase transfer mechanism, affording the corresponding bromoester products in good-to-excellent yields. The experimental process involved the reaction of Methyl 2-methyl-1H-indole-3-carboxylate(cas: 65417-22-3).SDS of cas: 65417-22-3

The Article related to lipophilic indole catalyst intermol bromoesterification olefin nonpolar media, bromoester preparation, General Organic Chemistry: Synthetic Methods and other aspects.SDS of cas: 65417-22-3

Referemce:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Candeias, Nuno R.; Carias, Carolina; Gomes, Luis F. R.; Andre, Vania; Duarte, M. Teresa; Gois, Pedro M. P.; Afonso, Carlos A. M. published an article in 2012, the title of the article was Asymmetric intramolecular C-H insertion of α-diazoacetamides in water by dirhodium(II) catalysts derived from natural amino acids.Product Details of 79815-20-6 And the article contains the following content:

The asym. dirhodium(II)-catalyzed intramol. C-H insertion of α-diazo acetamides in water is described for the first time. The use of natural α-amino acids as chiral ligands allowed the preparation of novel dirhodium(II) homochiral complexes by a simple procedure consisting of the in situ ligand exchange starting from dirhodium tetraacetate. The catalytic system was further reused up to 7 cycles and β-lactams were obtained in good yields and enantiomeric excess. The experimental process involved the reaction of H-Idc-OH(cas: 79815-20-6).Product Details of 79815-20-6

The Article related to lactam enantioselective preparation, diazoacetamide enantioselective cyclization rhodium catalyst, General Organic Chemistry: Synthetic Methods and other aspects.Product Details of 79815-20-6

Referemce:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

On July 27, 2020, Luo, Renshi; Chen, Miao-Miao; Ouyang, Lu; Chan, Albert S. C.; Lu, Gui published an article.SDS of cas: 79815-20-6 The title of the article was Enantioselective Reformatsky Reaction of Ketones Catalyzed by Chiral Indolinylmethanol. And the article contained the following:

A reliable and practical Reformatsky reaction of Et iodidoacetate with ketones for the synthesis of chiral β-hydroxyl carbonyl compounds in good yields and excellent enantioselectivities is presented. A readily available dihydroindole derivative was used as chiral catalyst, Et iodidoacetate was the nucleophile, and Me2Zn was the zinc source. The presence of air was found to be essential for the efficient construction of new carbon-carbon bonds through a radical pathway. The experimental process involved the reaction of H-Idc-OH(cas: 79815-20-6).SDS of cas: 79815-20-6

The Article related to enantioselective reformatsky ketone iodoacetate chiral indolinylmethanol catalyst, General Organic Chemistry: Synthetic Methods and other aspects.SDS of cas: 79815-20-6

Referemce:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

On July 31, 2010, Gandia-Herrero, Fernando; Escribano, Josefa; Garcia-Carmona, Francisco published an article.Application In Synthesis of H-Idc-OH The title of the article was Structural implications on color, fluorescence, and antiradical activity in betalains. And the article contained the following:

Betalains are water-soluble pigments with high anti-radical capacity which bestow bright colors on flowers and fruits of most plants of the order Caryophyllales. They are classified as betacyanins, exhibiting a violet coloration, and betaxanthins, which exhibit yellow coloration. Traditionally, betalains have been defined as condensation products of betalamic acid with different amines and amino acids, but the implication of the pigment structure for their properties has not been investigated. This paper explores different structural features of the betalains, revealing the clues for the switch from yellow to violet color, and the loss of fluorescence. A relevant series of 15 betalain-related compounds (both natural and novel semisynthetic ones) is obtained and characterized by chromatog., UV-vis spectrophotometry, fluorescence, and electrospray ionization mass spectroscopy. Anti-radical properties of individual pure compounds in a broad pH range are studied under the ABTS·+ radical assay. Relevance of specific bonds is studied, and differences between betaxanthins and betacyanins are used to explore in depth the structure-antiradical activity relationships in betalains. The experimental process involved the reaction of H-Idc-OH(cas: 79815-20-6).Application In Synthesis of H-Idc-OH

The Article related to flower color fluorescence antiradical antioxidant betalain betaxanthin betacyanin, Plant Biochemistry: Composition and Products and other aspects.Application In Synthesis of H-Idc-OH

Referemce:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

On June 16, 2011, Xiao, Jian; Xu, Feng-Xia; Lu, Yun-Peng; Liu, Yan-Ling; Loh, Teck-Peng published an article.Related Products of 79815-20-6 The title of the article was Highly efficient and modularly tuned bicyclic organocatalyst for the enantioselective Michael addition of aldehydes to nitroalkenes. And the article contained the following:

A new type of bicyclic catalyst has been successfully applied to the asym. Michael addition of aldehydes R1CH2CHO [R1 = Me, Et, n-Pr] to nitrostyrenes R2CH:CHNO2 [R2 = Ph, 4-BrC6H4, 2-furyl, etc.] to produce OHCCH(R1)CH(R2)CH2NO2 in good yields and good enantioselectivities by using a self-assembly strategy. The success of this reaction is attributed to good control of the geometry of the enamine and efficient face shielding. The experimental process involved the reaction of H-Idc-OH(cas: 79815-20-6).Related Products of 79815-20-6

The Article related to bicyclic catalyst enantioselective michael aldehyde nitroalkene, General Organic Chemistry: Synthetic Methods and other aspects.Related Products of 79815-20-6

Referemce:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

On November 3, 2000, Sato, S.; Watanabe, H.; Asami, M. published an article.Formula: C9H9NO2 The title of the article was Catalytic asymmetric borane reduction of prochiral ketones by the use of diazaborolidine catalysts prepared from chiral β-diamines. And the article contained the following:

The catalytic asym. borane reduction of prochiral ketones was examined in the presence of chiral diazaborolidine catalysts prepared in situ from chiral β-diamines and borane. Chiral secondary alcs. were obtained with modest to high enantiomeric excesses (up to 92% ee) using (S)-2-[[4-(trifluoromethyl)anilino]methyl]indoline. The experimental process involved the reaction of H-Idc-OH(cas: 79815-20-6).Formula: C9H9NO2

The Article related to asym reduction ketone diazaborolidine, General Organic Chemistry: Synthetic Methods and other aspects.Formula: C9H9NO2

Referemce:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Huang, Xu-Lun; Cheng, Yuan-Zheng; You, Shu-Li published an article in , the title of the article was Visible-light enabled synthesis of cyclopropane-fused indolines via dearomatization of indoles.HPLC of Formula: 65417-22-3 And the article contains the following content:

An efficient synthesis of methylene-unsubstituted cyclopropane-fused indolines I (R1 = H, 2-Br, 3-Me, etc.; X = N, CH; R2 = H, CO2Me, Ac, 2-hydroxyethyl; R3 = H, Me; R4 = Boc, Ts, Ac, 4-acetyl-10,10-dimethyl-3-thia-4-azatricyclodecane-3,3-dione) and (R)-1a-((1R,5S)-10,10-dimethyl-3,3-dioxo-3lambda*6*-thia-4-aza-tricyclo[5.2.1.0*1,5*]decane-4-carbonyl)-1a,6a-dihydro-1H-6-aza-cyclopropa[a]indene-6-carboxylic acid tert-Bu ester via photoredox catalyzed dearomative cyclopropanation of indole derivatives II was developed. A broad range of indoles bearing a variety of functional groups was compatible with these mild conditions, affording the products in moderate to excellent yields. Asym. cyclopropanation was also realized with the assistance of a chiral auxiliary in good yield with excellent diastereoselectivity, followed by the removal of the auxiliary to give enantioenriched alc. I. The 5 mmol scale reaction and derivatizations of the products I were successfully carried out to demonstrate the synthetic value of this reaction. The experimental process involved the reaction of Methyl 2-methyl-1H-indole-3-carboxylate(cas: 65417-22-3).HPLC of Formula: 65417-22-3

The Article related to cyclopropane indoline preparation diastereoselective, indole preparation iodomethylsilicate dearomative cyclopropanation photoredox catalyst, Placeholder for records without volume info and other aspects.HPLC of Formula: 65417-22-3

Referemce:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Huo, Li-chun; Liu, Sheng-li; Li, Chun-xin published an article in 2015, the title of the article was Synthesis process of (S)-indoline-2-carboxylic acid.Recommanded Product: H-Idc-OH And the article contains the following content:

Synthesis process of (S)-indoline-2-carboxylic acid was investigated, where di-Et oxalate and o-nitrotoluene were taken as raw material to generate an intermediate the Et o-nitrophenylpyruvate under the action of potassium ethoxide. The target product (S)-indoline-2-carboxylic acid was obtained from Et o-nitrophenylpyruvate by nickel-catalytic hydrogenation, magnesium powder reduction and chiral separation The overall yield is 38%(based on o-nitrotoluene). This synthesis process is low in cost and environmental pollution. The experimental process involved the reaction of H-Idc-OH(cas: 79815-20-6).Recommanded Product: H-Idc-OH

The Article related to indoline carboxylic acid synthesis chiral separation nickel catalytic hydrogenation, Placeholder for records without volume info and other aspects.Recommanded Product: H-Idc-OH

Referemce:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles