Tag: M.W=100-150

Recently I am researching about EARLY PREDICTION ASSAY; MOUSE LYMPHOMA CELL; SYNTHESIS RDS TEST; BENZYL ALCOHOL; MUTATION ASSAY; PERSONAL CARE; HUMAN-SKIN; PERCUTANEOUS-ABSORPTION; DEVELOPMENTAL TOXICITY; PEPTIDE REACTIVITY, Saw an article supported by the . Published in PERGAMON-ELSEVIER SCIENCE LTD in OXFORD ,Authors: Api, AM; Belsito, D; Biserta, S; Botelho, D; Bruze, M; Burton, GA; Buschmann, J; Cancellieri, MA; Dagli, ML; Date, M; Dekant, W; Deodhar, C; Fryer, AD; Gadhia, S; Jones, L; Joshi, K; Lapczynski, A; Lavelle, M; Liebler, DC; Na, M; O’Brien, D; Patel, A; Penning, TM; Ritacco, G; Rodriguez-Ropero, F; Romine, J; Sadekar, N; Salvito, D; Schultz, TW; Siddiqi, F; Sipes, IG; Sullivan, G; Thakkar, Y; Tokura, Y; Tsang, S. The CAS is 100-51-6. Through research, I have a further understanding and discovery of Benzyl Alcohol. SDS of cas: 100-51-6

The existing information supports the use of this material as described in this safety assessment. p-Isopropylbenzyl alcohol was evaluated for genotoxicity, repeated dose toxicity, developmental and reproductive toxicity, local respiratory toxicity, phototoxicity/photoallergenicity, skin sensitization, and environmental safety. Data from the read-across analog benzyl alcohol (CAS # 100-51-6) show that p-isopropylbenzyl alcohol is not expected to be genotoxic. Data from the read-across analog benzyl alcohol (CAS # 100-51-6) provide a calculated MOE > 100 for the repeated dose, developmental, and local respiratory toxicity endpoints. The reproductive toxicity endpoint was evaluated using the ITC for a Cramer Class I material, and the exposure is below the ITC (0.03 mg/kg/day). Data from read-across analog benzyl alcohol (CAS # 100-51-6) provided p-isopropylbenzyl alcohol a NESIL of 5900 mu g/cm(2) for the skin sensitization endpoint. The phototoxicity and photoallergenicity endpoints were evaluated based on UV spectra; p-isopropylbenzyl alcohol is not expected to be phototoxic/photoallergenic. The environmental endpoints were evaluated; p-isopropylbenzyl alcohol was found not to be a PBT as per the IFRA Environmental Standards, and its risk quotients, based on its current volume of use in Europe and North America (i.e., PEC/PNEC) are < 1. SDS of cas: 100-51-6. About Benzyl Alcohol, If you have any questions, you can contact Api, AM; Belsito, D; Biserta, S; Botelho, D; Bruze, M; Burton, GA; Buschmann, J; Cancellieri, MA; Dagli, ML; Date, M; Dekant, W; Deodhar, C; Fryer, AD; Gadhia, S; Jones, L; Joshi, K; Lapczynski, A; Lavelle, M; Liebler, DC; Na, M; O’Brien, D; Patel, A; Penning, TM; Ritacco, G; Rodriguez-Ropero, F; Romine, J; Sadekar, N; Salvito, D; Schultz, TW; Siddiqi, F; Sipes, IG; Sullivan, G; Thakkar, Y; Tokura, Y; Tsang, S or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

An article Low-Temperature Intramolecular [4+2] Cycloaddition of Allenes with Arenes for the Synthesis of Diene Ligands WOS:000607557500001 published article about DIELS-ALDER REACTION; CATALYZED OXY-ALKYNYLATION; CHIRAL LIGANDS; ALLENECARBOXANILIDES; REARRANGEMENT; REACTIVITY in [Hari, Durga Prasad; Pisella, Guillaume; Wodrich, Matthew D.; Tsymbal, Artem, V; Waser, Jerome] Ecole Polytech Fed Lausanne, EPFL SB ISIC LCSO, Lab Catalysis & Organ Synth, BCH 1402, CH-1015 Lausanne, Switzerland; [Hari, Durga Prasad] Ecole Polytech Fed Lausanne, Inst Chem & Chem Engn, EPFL SB ISIC GE, BCH 2111, CH-1015 Lausanne, Switzerland; [Tirani, Farzaneh Fadaei; Scopelliti, Rosario] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England in 2021.0, Cited 56.0. Product Details of 150-76-5. The Name is Mequinol. Through research, I have a further understanding and discovery of 150-76-5

The intramolecular [4+2] cycloaddition between arenes and allenes first reported by Himbert gives rapid access to rigid polycyclic scaffolds. Herein, we report a one-pot oxyalkynylation/cycloaddition reaction proceeding under mild conditions (23-90 degrees C) and providing complex polycyclic architectures with high efficiency, and atom and step economy. The bicyclo[2.2.2]octadiene products were obtained with a wide variety of useful functional groups and were successfully applied as chiral ligands for metal catalysis. Computational studies gave a first rationalization of the low activation energy for the cycloaddition based on counter-intuitive favorable dispersive interactions in the transition state.

Product Details of 150-76-5. About Mequinol, If you have any questions, you can contact Hari, DP; Pisella, G; Wodrich, MD; Tsymbal, AV; Tirani, FF; Scopelliti, R; Waser, J or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Dejardin, C; Renou, A; Maddaluno, J; Durandetti, M in [Dejardin, Claire; Renou, Amaury; Maddaluno, Jacques; Durandetti, Muriel] Normandie Univ, UNIROUEN, INSA Rouen, CNRS,Lab COBRA UMR 6014 & FR 3038, F-76000 Rouen, France published Nickel-Catalyzed Electrochemical Cyclization of Alkynyl Aryl Iodide and the Domino Reaction with Aldehydes in 2021, Cited 42. Recommanded Product: 4-Methoxybenzaldehyde. The Name is 4-Methoxybenzaldehyde. Through research, I have a further understanding and discovery of 123-11-5.

An intramolecular carbometallation of a triple bond promoted by electrochemistry and mediated by nickel catalysis is described. This domino process transforms various aryl halides bearing a propargyl chain into substituted heterocycles in one single operation, with high stereoselectivities and in good to high yields. This reaction, characterized by a cyclic voltammetry set of experiments, proceeds following a syn-exo-dig cyclization process. When run at 80 degrees C, vinylbenzofuranes that are suitable substrates for cycloaddition reactions are obtained.

Recommanded Product: 4-Methoxybenzaldehyde. About 4-Methoxybenzaldehyde, If you have any questions, you can contact Dejardin, C; Renou, A; Maddaluno, J; Durandetti, M or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Authors Mehta, J; Aryal, P; Reddy, VP in WILEY-V C H VERLAG GMBH published article about METAL-FREE; NUCLEOPHILIC TRIFLUOROMETHYLATION; ASYMMETRIC-SYNTHESIS; KETONES; AMINES; IMINES in [Mehta, Jatin; Aryal, Puspa; Prakash Reddy, V.] Missouri Univ Sci & Technol, Dept Chem, Rolla, MO 65409 USA in 2021, Cited 39. Category: indole-building-block. The Name is 4-Methoxybenzaldehyde. Through research, I have a further understanding and discovery of 123-11-5

The C(sp(2)-H)-trifluoromethylation of hydrazones would give access to the alpha-trifluoromethylated hydrazones that can serve as intermediates in the synthesis of pharmaceutically interesting fluorinated compounds. Herein, we demonstrate the Cu-catalyzed C(sp(2)-H)-trifluoromethylation of the aldehyde hydrazones using the readily available and cost effective Langlois reagent (sodium trifluoromethanesulfinate). This reaction is broadly applicable to a series of aromatic aldehyde N-aminomorpholine hydrazones to give the corresponding C(sp(2))-trifluoromethyl hydrazones in moderate to high yields. The reaction generally tolerates a series of electron-releasing as well as electron-withdrawing substituents on the aromatic ring.

About 4-Methoxybenzaldehyde, If you have any questions, you can contact Mehta, J; Aryal, P; Reddy, VP or concate me.. Category: indole-building-block

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Recommanded Product: 100-51-6. Recently I am researching about N-BUTANOL; ETHANOL; FUEL; PROGRESS, Saw an article supported by the . Published in ELSEVIER SCI LTD in OXFORD ,Authors: Geo, VE; Godwin, DJ; Thiyagarajan, S; Saravanan, CG; Aloui, F. The CAS is 100-51-6. Through research, I have a further understanding and discovery of Benzyl Alcohol

This investigation mainly focuses on the characteristic study on combustion, performance and emission of gasoline blended with lower order alcohol, i.e. ethanol and higher order alcohol, i.e. benzyl alcohol in the ratio of 10% and 20% by volume of the overall quantity. These two alcohols were blended with gasoline and investigated solely to find the comparison between higher and lower order alcohols and thus to identify the optimum blend based on the performance and emission characteristics. The blends were tested in a commercial two-cylinder 624 cc gasoline engine with multi-point fuel injection (MPFI) system and data acquisition capability. The fuel blends were tested at different loads ranging from 20% to 100% with a step size of 20% in ascending sequence. At full load, higher alcohol blend showed an improvement in brake thermal efficiency (BTE) of 32.8% and 33.2% for Bn10 and Bn20, when compared to neat gasoline 29.77% and BTE of lower alcohol registered a slight improvement in comparison to gasoline, i.e. 30.41% and 31.1% for E10 and E20 respectively. HC emissions were reduced to 70 ppm and 57 ppm for lower and higher alcohol blends respectively, which is lower compared to 88 ppm for gasoline. CO and CO2 emissions were reduced with both lower and higher alcohol blends in comparison with neat gasoline. NOx emissions show a reduction nature with alcohol blends when compared to neat gasoline at all the load conditions. It is perceived that based on the performance, emission and combustion characteristics, higher alcohol namely benzyl alcohol blend with gasoline is optimum.

About Benzyl Alcohol, If you have any questions, you can contact Geo, VE; Godwin, DJ; Thiyagarajan, S; Saravanan, CG; Aloui, F or concate me.. Recommanded Product: 100-51-6

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

COA of Formula: C7H8O. In 2019.0 ORG LETT published article about DONOR-ACCEPTOR COMPLEXES; RADICAL CHAIN REACTIONS; H BOND ACTIVATION; ORGANIC-COMPOUNDS; ELECTRON-TRANSFER; CYANINE DYES; METAL-FREE; C-F; ALPHA-CHLORINATION; FACILE ACCESS in [Rathnayake, Manjula D.; Weaver, Jimmie D., III] Oklahoma State Univ, Dept Chem, 107 Phys Sci, Stillwater, OK 74078 USA in 2019.0, Cited 88.0. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6.

Net selective bromination and chlorination of activated C-H bonds can be effected in generally high yield via a simple perhalogenation/dehalogenation sequence. The photochemical reductions require no photocatalyst, relying instead on the formation of an electron donor-acceptor complex of the substrate and reductant, or alternatively autophotocatalysis. Some reactions proceed despite any apparent photon absorption, serving as a cautionary tale for other photochemical reactions involving amines. Mechanistic experiments provide an explanation for this observation.

About Benzyl Alcohol, If you have any questions, you can contact Rathnayake, MD; Weaver, JD or concate me.. COA of Formula: C7H8O

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Recently I am researching about ONE-POT SYNTHESIS; WACKER-TYPE OXIDATION; CATALYZED OXIDATION; ARYLBORONIC ACIDS; ENDOPHYTIC FUNGUS; PRACTICAL METHOD; BOND FORMATION; COPPER; TBHP; ALKENES, Saw an article supported by the Ministry of Science and Technology of the Republic of ChinaMinistry of Science and Technology, China [MOST 109-2113-M-037-014-MY3]. SDS of cas: 100-83-4. Published in GEORG THIEME VERLAG KG in STUTTGART ,Authors: Chang, MY; Lai, KX; Chen, KT. The CAS is 100-83-4. Through research, I have a further understanding and discovery of 3-Hydroxybenzaldehyde

A concise route for the (BuO2H)-Bu-t/Cu(acac)(2)-mediated synthesis of 1-oxoisochromans is described. This includes: (i) oxidation of oxygenated o-allyl arylaldehydes and (ii) sequential intramolecular lactonization of the resulting olefin-containing benzoic acids. A plausible mechanism is proposed and discussed.

SDS of cas: 100-83-4. About 3-Hydroxybenzaldehyde, If you have any questions, you can contact Chang, MY; Lai, KX; Chen, KT or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Product Details of 123-11-5. Authors Kargar, S; Elhamifar, D; Zarnegaryan, A in ELSEVIER published article about in [Kargar, Shiva; Elhamifar, Dawood; Zarnegaryan, Ali] Univ Yasuj, Dept Chem, Yasuj 7591874831, Iran in 2021, Cited 83. The Name is 4-Methoxybenzaldehyde. Through research, I have a further understanding and discovery of 123-11-5

A novel ionic liquid modified graphene oxide supported Mo-complex [GO@IL/MoO2(acae)(2)] was successfully prepared, characterized and its catalytic application was investigated. The GO@IL/MoO2(acae)(2) catalyst was prepared through the surface modification of graphene oxide with alkyl imidazolium chloride followed by treatment with molybdenyl acetylacetonate. The GO@IL/MoO2(acae)(2) catalyst was characterized by using FT-IR, PXRD, TGA, EDX, and SEM analyses. This catalyst showed high activity in the green production of pyrazolo[b] phthalazine dione derivatives under ultrasonic conditions. The designed catalyst was effectively recovered and successfully reused at least eight times without significant loss in its efficiency.

Product Details of 123-11-5. About 4-Methoxybenzaldehyde, If you have any questions, you can contact Kargar, S; Elhamifar, D; Zarnegaryan, A or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Recommanded Product: 100-51-6. In 2019 EUR J INORG CHEM published article about HETEROCYCLIC CARBENE; BORROWING HYDROGEN; BETA-ALKYLATION; SECONDARY ALCOHOLS; BOND ACTIVATION; RUTHENIUM CATALYSTS; IRIDIUM COMPLEX; AMINATION; DEHYDROGENATION; TERTIARY in [Kaloglu, Nazan; Ozdemir, Ismail] Inonu Univ, Fac Sci & Art, Dept Chem, TR-44280 Malatya, Turkey; [Kaloglu, Nazan; Ozdemir, Ismail] Inonu Univ, Catalysis Res & Applicat Ctr, TR-44280 Malatya, Turkey; [Achard, Mathieu; Bruneau, Christian] Rennes Univ, CNRS, ISCR, UMR6226, F-35000 Rennes, France in 2019, Cited 113. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6.

A series of unsymmetrical 1,3-disubstituted benzimidazolium chlorides were synthesized as N-heterocyclic carbene (NHC) precursors. These compounds were used for synthesis of the new ruthenium(II) complexes of the type [RuCl2(arene)(NHC)], (arene = eta(6)-p-cymene). The structures of all compounds were characterized by H-1 NMR, C-13 NMR and FT-IR spectroscopy techniques. The catalytic activity of the ruthenium complexes has been evaluated with respect to the mono-N-alkylation reactions of aromatic amines with various alcohol derivatives under solvent-free conditions at 120 degrees C using the borrowing hydrogen strategy.

Recommanded Product: 100-51-6. About Benzyl Alcohol, If you have any questions, you can contact Kaloglu, N; Achard, M; Bruneau, C; Ozdemir, I or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

COA of Formula: C7H8O2. I found the field of Chemistry very interesting. Saw the article ARS-TiO2 photocatalyzed direct functionalization of sp2 C-H bonds toward thiocyanation and cyclization reactions under visible light published in 2020.0, Reprint Addresses Hosseini-Sarvari, M (corresponding author), Shiraz Univ, Dept Chem, Shiraz 7194684795, Iran.. The CAS is 150-19-6. Through research, I have a further understanding and discovery of m-Methoxyphenol.

An ARS-TiO2 photocatalyst has been prepared, by a simple method through stirring a mixture of ARS and TiO2 at room temperature in the dark, to extend the photocatalytic response of titanium dioxide toward the visible light spectrum. The synergic effect of ARS and TiO2 in the photocatalyst system has catalyzed direct C-H functionalization of sp2 C-H bonds toward thiocyanation and cyclization reactions. Several aromatic and heteroaromatic scaffolds (2-phenylamino-thiazole, phenol, aniline, indole and pyrrole derivatives) were treated with the thiocyanate anion at room temperature. Herein, the first report on thiocyanation of phenol and synthesis of 2-aminobenzothiazole derivatives under visible light is presented.

COA of Formula: C7H8O2. About m-Methoxyphenol, If you have any questions, you can contact Koohgard, M; Hosseinpour, Z; Sarvestani, AM; Hosseini-Sarvari, M or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles