Tag: M.W=100-150

An article Synthesis of Novel 6-Aryloxy-4-chloro-2-phenylpyrimidines as Fungicides and Herbicide Safeners WOS:000575417400054 published article about ANTIFUNGAL ACTIVITY; DESIGN; PYRIMETHANIL; DERIVATIVES; INHIBITOR in [Deng, Xile; Zheng, Wenna; Jin, Can; Bai, Lianyang] Hunan Acad Agr Sci, Hunan Agr Biotechnol Res Inst, Key Lab Biol & Control Weeds, Changsha 410125, Peoples R China in 2020, Cited 68. The Name is m-Methoxyphenol. Through research, I have a further understanding and discovery of 150-19-6. Quality Control of m-Methoxyphenol

Fenclorim is a commercial herbicide safener with fungicidal activity used for chloroacetanilide herbicides, which might be suitable as a lead compound for screening novel fungicides. However, little has been reported so far on the structure-activity relationship of fungicidal activities of fenclorim or its analogues. Here, a series of 4-chloro-6-substituted phenoxy-2-phenylpyrimidine derivatives was synthesized by a substructure splicing route using fenclorim as a lead compound. The structures of synthesized derivatives were characterized by H-1 NMR, C-13 NMR, and HRMS. Their fungicidal and herbicide safening activities were then evaluated. The results revealed that compound 11 had the best fungicidal activity against Sclerotinia sclerotiorum and Thanatephorus cucumeris, which was better than that of the control pyrimethanil. Moreover, compounds 3, 5, and 25 exhibited excellent safening activities against fresh weight, plant height, and root length, respectively. Such activities were significantly improved when compared to fenclorim. In summary, these findings look promising for the preparation of new fungicides and herbicide safeners based on the structure of fenclorim.

Quality Control of m-Methoxyphenol. About m-Methoxyphenol, If you have any questions, you can contact Deng, XL; Zheng, WN; Jin, C; Bai, LY or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

An article Ru-Catalyzed (E)-Specific ortho-C-H Alkenylation of Arenecarboxylic Acids by Coupling with Alkenyl Bromides WOS:000649477300059 published article about DIRECT ORTHO ARYLATION; CARBOXYLIC-ACIDS; BENZOIC-ACIDS; BOND; PALLADIUM; HYDROARYLATION; OLEFINATION; ARYL; ALKYNES; ACTIVATION in [Hu, Zhiyong; Belitz, Florian; Zhang, Guodong; Papp, Florian; Goossen, Lukas J.] Ruhr Univ Bochum, Evonik Chair Organ Chem, D-44801 Bochum, Germany in 2021, Cited 68. The Name is (E)-2-Methylbut-2-enoic acid. Through research, I have a further understanding and discovery of 80-59-1. Safety of (E)-2-Methylbut-2-enoic acid

In the presence of [p-cymene)RuCl2](2), (E)-configured alkenyl bromides couple with aromatic carboxylates to form orthovinylbenzoic acids. This C-H vinylation proceeds in high yields without any activating phosphine ligands and has an excellent functional group tolerance. Starting from commonly available (E/Z)-mixtures of alkenyl bromides, (E)-configured vinyl arenes or dienes are formed exclusively. Mechanistic studies show that this selectivity is achieved because the (E)configured alkenyl bromides undergo a smooth coupling, whereas the (Z)-isomers are rapidly eliminated with the formation of alkynes.

Safety of (E)-2-Methylbut-2-enoic acid. About (E)-2-Methylbut-2-enoic acid, If you have any questions, you can contact Hu, ZY; Belitz, F; Zhang, GD; Papp, F; Goossen, LJ or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Recently I am researching about SINGLE-ELECTRON TRANSMETALATION; CYCLIZATIONS; AMINATION; ALCOHOLS; HALIDES; KETONES; DIENES, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21772208, 21702212, 21633013]; Natural Science Foundation of Jiangsu ProvinceNatural Science Foundation of Jiangsu Province [BK20201183]; Key Research Program of Frontier Sciences of CAS [QYZDJSSW-SLH051]. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Li, YL; Zhang, SQ; Chen, J; Xia, JB. The CAS is 123-11-5. Through research, I have a further understanding and discovery of 4-Methoxybenzaldehyde. Recommanded Product: 123-11-5

A Co-catalyzed highly regio- and enantioselective reductive coupling of alkynes and aldehydes has been developed under visible light photoredox dual catalysis. A variety of enantioenriched allylic alcohols have been obtained by using unsymmetrical internal alkynes and commercially available catalyst, chiral ligand, and reagents. It is noteworthy that this approach has considerable advantages, such as excellent regio- (>95:5 for >40 examples), stereo- (up to >95:5 E/Z), and enantioselectivity (92-99% ee, >35 examples) control, mild reaction conditions, broad substrate scope, and good functional group compatibility, making it a great improvement to enantioselective alkyne-aldehyde reductive coupling reactions.

Recommanded Product: 123-11-5. About 4-Methoxybenzaldehyde, If you have any questions, you can contact Li, YL; Zhang, SQ; Chen, J; Xia, JB or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

An article Magnetically recoverable graphene oxide supported Co@Fe3O4/L-dopa for C-C cross-coupling and oxidation reactions in aqueous medium WOS:000466253900004 published article about HIGHLY EFFICIENT; CATALYST; SUZUKI; REDUCTION; NANOPARTICLES; NANOCATALYSTS; HECK; NITROAROMATICS; NANOCOMPOSITE; COMPOSITE in [Sharma, Harsha; Sharma, Shally; Sharma, Chandan; Paul, Satya] Univ Jammu, Dept Chem, Jammu 180006, Jammu & Kashmir, India; [Clark, James H.] Univ York, Dept Chem, Green Chem Ctr Excellence, York YO10 5DD, N Yorkshire, England in 2019, Cited 50. Safety of 4′-Hydroxyacetophenone. The Name is 4′-Hydroxyacetophenone. Through research, I have a further understanding and discovery of 99-93-4

We report the synthesis of inexpensive and environmentally benign cobalt(0) nanoparticles on L-3,4-dihydroxyphenylalanine (L-dopa) functionalized and magnetite (Fe3O4) grafted graphene oxide (Co@GO/Fe3O4/L-dopa) which was fully characterized with different techniques such as Scanning Electron Microscopy (SEM), High Resolution Transmission Electron Microscopy (HR-TEM), X-Ray Photoelectron Spectroscopy (XPS), X-ray Powder Diffraction (XRD), Thermogravimetric analysis (TGA), Fourier Transform Infrared Spectroscopy (FTIR), Vibrating Sample Magnetometer (VSM), Carbon Hydrogen Nitrogen (CHN) analysis, Energy Dispersive X-ray (EDX) and Inductively Coupled Plasma Atomic Emission Spectroscopy (ICP-AES). Graphene oxide was used as the core material due to its mechanical, electrical and thermal properties. In order to avoid the cumbersome process of separation, magnetite nanoparticles were coated over the graphene oxide. After the successful preparation of graphene oxide based magnetic nanoparticles, L-dopa was grafted over Fe3O4 nanoparticles so as to provide firm anchoring agent for cobalt nanoparticles. Finally, cobalt(0) nanoparticles were immobilized on the developed magnetic support. The catalytic efficiency of the synthesized catalyst was tested for Suzuki cross-coupling and oxidation reactions, usually carried out by precious and expensive second and third row transition metals; products were obtained in good to excellent yields. The synthesized catalyst represents an attractive alternative to conventional catalysts for Suzuki cross-coupling and oxidation reactions, and is recyclable up to five runs.

About 4′-Hydroxyacetophenone, If you have any questions, you can contact Sharma, H; Sharma, S; Sharma, C; Paul, S; Clark, JH or concate me.. Safety of 4′-Hydroxyacetophenone

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

An article CE with multi-walled carbon nanotubes (MWCNTs). Part I. Functionalized and SDS coated MWCNTs as pseudo-stationary phases in nanoparticle EKC – Studies on retention energetics WOS:000449443900071 published article about ELECTROKINETIC CAPILLARY CHROMATOGRAPHY; PSEUDOSTATIONARY PHASE; ACID CATALYST; ELECTROPHORESIS; SEPARATION; NANOMATERIALS; PROTONATION; RAMAN in [Alharthi, Sarah; El Rassi, Ziad] Oklahoma State Univ, Dept Chem, Stillwater, OK 74078 USA in 2019, Cited 33. Safety of Benzyl Alcohol. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6

In this study, multi-walled carbon nanotubes (MWCNTs) in either unmodified, hydroxylated (MWCNT-OH), carboxylated (MWCNT-COOH) or sulfonated (MWCNT-SO3H) forms were incorporated into the running electrolytes in capillary electrophoresis (CE) to play the role of pseudo-stationary phases (PSPs) and perform nanoparticle electrokinetic capillary chromatography (NPEKC). MWCNT-COOH and MWCNT-SO3H were derived from MWCNTs via their treatment with concentrated strong acids. These functionalized MWCNTs were characterized by Raman and FTIR spectroscopies to demonstrate their covalent functionalization. The study of MWCNT-SO3H and MWCNT-OH as PSPs were introduced in this research report for the first time in NPEKC. The results obtained with functionalized MWCNTs were compared to those obtained using unmodified MWCNTs for better understanding the electrophoretic behavior of these functionalized MWCNTs. While only MWCNT-COOH allowed the separation of some nucleic acid bases and nucleosides, neutral solutes such as alkylbenzenes (ABs), phenyl alkyl alcohols (PAAs) and aniline derivatives in neutral forms (i.e., at basic pH) were not resolved in the presence of neither MWCNT-COOH nor MWCNT-SO3H in the running electrolytes, indicating that these functionalized MWCNTs do not have enough surface charge density to function as effective PSPs in NPEKC. This necessitated the coating of the functionalized MWCNTs under investigation with sodium dodecyl sulfate (SDS) to bring about the separation of neutral solutes by NPEKC. The SDS coated MWCNTs whether unmodified or functionalized were characterized with two homologous series namely ABs and PAAs in order to evaluate their relative retention energetics under the same electrolyte composition. The results showed that the systems pairs SDS-MWCNT-COOH/SDS-MWCNTs and SDS-MWCNT-OH/SDS-MWCNTs were homoenergetics (i.e., same energetics) while the system pair SDS-MWCNT-SO3H/SDS-MWCNTs was homeoenergetics (i.e., similar energetics). On the other hand, all the systems pairs SDS coated MWCNTs/SDS were homeoenergetics. Homoenergetics means that the solute retention has an identical physico-chemical basis and the differences observed in the magnitude of solute retention on the various PSPs are attributed to differences in the nonpolar phase ratios of the PSPs under otherwise the same electrolyte composition. Conversely, homeoenergetics signifies that the solute retention has a similar physico-chemical basis in the PSPs systems under investigation, which also differ in their phase ratios.

Safety of Benzyl Alcohol. About Benzyl Alcohol, If you have any questions, you can contact Alharthi, S; El Rassi, Z or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Recommanded Product: 80-59-1. In 2019 J PHYS CHEM B published article about HALOGEN BONDS; CHOLINE CHLORIDE; PNICOGEN BONDS; BASIS-SETS; HYDROGEN; COMPLEXES; SOLVENTS; CHEMISTRY; CHALCOGEN; GLYCEROL in [Yu, Dongkun; Mu, Tiancheng] Renmin Univ China, Dept Chem, Beijing 100872, Peoples R China in 2019, Cited 52. The Name is (E)-2-Methylbut-2-enoic acid. Through research, I have a further understanding and discovery of 80-59-1.

The concept of eutectic molecular liquids (EMLs) was defined, and a strategy to form EMLs based on noncovalent interactions was proposed. We verified the formation and investigated the properties, interaction sites, and interaction energies of the obtained 16 EMLs. Moreover, two new forms of noncovalent interactions, kappa-hole and mu-hole bonding interactions, were proposed, which broaden the understanding of intermolecular interactions. Numerous EMLs can be strategically designed and prepared by simply mixing two parent molecule components based on noncovalent interactions, including hydrogen bonding interactions; pi-pi stacking; and sigma-hole (halogen, chalcogen, pnicogen, and tetrel bonds), pi-hole, kappa-hole, and mu-hole bonding interactions. The properties of EMLs can be finely tailored by selecting or even designing appropriate parent compounds for task-specific applications. Our work presents a substantial step toward the innovative development of liquid systems.

Recommanded Product: 80-59-1. About (E)-2-Methylbut-2-enoic acid, If you have any questions, you can contact Yu, DK; Mu, TC or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

An article Detoxification of host plant phenolic aglycones by the spruce budworm WOS:000468030100002 published article about GLUTATHIONE-S-TRANSFERASE; HELICOVERPA-ARMIGERA; MIDGUT; RESISTANCE; ECOLOGY; TANNINS; PH in [Donkor, Dominic; Mirzahosseini, Zahra; Despland, Emma] Concordia Univ, Biol Dept, Montreal, PQ, Canada; [Bede, Jacquie] McGill Univ, Dept Plant Sci, Ste Anne De Bellevue, PQ, Canada; [Bauce, Eric] Univ Laval, Dept Sci Bois & Foret, Ste Foy, PQ, Canada in 2019.0, Cited 40.0. The Name is 4′-Hydroxyacetophenone. Through research, I have a further understanding and discovery of 99-93-4. COA of Formula: C8H8O2

This study examines the post-ingestive fate of two host-plant derived small-molecule phenolics (the acetophenones piceol and pungenol) that have previously been shown to be toxic to the outbreaking forest pest, spruce budworm (Choristoneura fumiferana). We test first whether these compounds are transformed during passage through the midgut, and second whether the budworm upregulates activity of the detoxification enzyme glutathione-s-transferase (GST) in response to feeding on these compounds. Insects were reared on either foliage or artificial diet to the fourth instar, when they were transferred individually to one of two treatment diets, either control or phenolic-laced, for approximately 10 days, after which midguts were dissected out and used for Bradford soluble protein and GST enzyme activity analysis. Frass was collected and subjected to HPLC-DAD-MS. HPLC showed that the acetophenones do not autoxidize under midgut pH conditions, but that glucose- and glutathione-conjugates are present in the frass of insects fed the phenolic-laced diet. GST enzyme activity increases in insects fed the phenolic-laced diet, in both neutral pH and alkaline assays. These data show that the spruce budwom exhibits counter-adaptations to plant phenolics similar to those seen in angiosperm feeders, upregulating an important detoxifying enzyme (GST) and partially conjugating these acetophenones prior to elimination, but that these counter-measures are not totally effective at mitigating toxic effects of the ingested compounds in the context of our artifical-diet based laboratory experiment.

COA of Formula: C8H8O2. About 4′-Hydroxyacetophenone, If you have any questions, you can contact Donkor, D; Mirzahosseini, Z; Bede, J; Bauce, E; Despland, E or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Espinoza-Hicks, JC; Chacon-Vargas, KF; Hernandez-Rivera, JL; Nogueda-Torres, B; Tamariz, J; Sanchez-Torres, LE; Camacho-Davila, A in [Espinoza-Hicks, Jose C.; Hernandez-Rivera, Jessica L.; Camacho-Davila, Alejandro] Univ Autonoma Chihuahua, Fac Ciencias Quim, Campus Univ,Apartado Postal 669, Chihuahua, Chih, Mexico; [Fabiola Chacon-Vargas, Karla; Enid Sanchez-Torres, Luvia] Inst Politecn Nacl, Escuela Nacl Ciencias Biol, Dept Inmunol, Prolongac Carpio & Plan de Ayala S-N, Mexico City 11340, DF, Mexico; [Fabiola Chacon-Vargas, Karla; Nogueda-Torres, Benjamin] Inst Politecn Nacl, Escuela Nacl Ciencias Biol, Dept Parasitol, Prolongac Carpio & Plan de Ayala S-N, Mexico City 11340, DF, Mexico; [Tamariz, Joaquin] Inst Politecn Nacl, Escuela Nacl Ciencias Biol, Dept Quim Organ, Prolongac Carpio & Plan de Ayala S-N, Mexico City 11340, DF, Mexico published Novel prenyloxy chalcones as potential leishmanicidal and trypanocidal agents: Design, synthesis and evaluation in 2019.0, Cited 43.0. Category: indole-building-block. The Name is 4′-Hydroxyacetophenone. Through research, I have a further understanding and discovery of 99-93-4.

The available drugs for treating Leishmaniasis and American trypanosomiasis have high toxicity and multiple side effects, among other problems. More effective and less toxic treatments are urgently needed. A series of chalcones that contained a prenyloxy or geranyloxy substituent was synthesized and characterized. Each substituent was attached to the A ring in some compounds and to the B ring in others, with additional substituents placed on the chalcone moiety. The present aim was to evaluate the effect of the substitution pattern on leishmanicidal and trypanocidal activity. When tested at a single concentration, the compounds exerting a metabolic inhibition close to or exceeding 50% for Leishmania mexicana were 11, 17 and 12, and for Trypanosoma cruzi were 11, 17, 15 and 26. Upon determining the selectivity index (SI =IC50/CC50), the values were 80.9, 1.24 and 55.12 for 11, 17 and 12 (respectively) versus L mexicana, and 75.1, 1.43, 27.36 and 33.52 for 11, 17, 15 and 26 (respectively) versus T. cruzi. Structural isomers 11 and 17 showed activity for both the L mexicana and T. cruzi strains, though the greater cytotoxic activity of 17 led to a lower SI. Compounds 12, 15 and 26 were species specific. For I cruzi, the SI was higher for 11, 15 and 26 than for the reference drugs nifurtimox and benznidazole. The examination of promastigote morphology after exposing L mexicana and T. cruzi to 11 revealed a decrease in cell density. The current findings suggest that 11 could be a useful lead compound for further SAR studies. (C) 2019 Elsevier Masson SAS. All rights reserved.

Category: indole-building-block. About 4′-Hydroxyacetophenone, If you have any questions, you can contact Espinoza-Hicks, JC; Chacon-Vargas, KF; Hernandez-Rivera, JL; Nogueda-Torres, B; Tamariz, J; Sanchez-Torres, LE; Camacho-Davila, A or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Authors Peng, XB; He, D; Sun, GN; Yu, Y; Ma, YH; Tang, SA; Dong, WL; Li, SY in AMER CHEMICAL SOC published article about in [Peng, Xin-Bang; He, Di; Yu, Yu; Ma, Ying-Hong; Tang, Sheng-An; Dong, Wei-Li; Li, Shao-Yong] Tianjin Med Univ, Sch Pharm, Tianjin 300070, Peoples R China; [Sun, Guan-Nan] Tianjin Med Univ, Gen Hosp, Tianjin 300070, Peoples R China; [Sun, Guan-Nan] Tianjin Vocat Coll Bioengn, Tianjin 300462, Peoples R China in 2021, Cited 52. Application In Synthesis of 4-Methoxybenzaldehyde. The Name is 4-Methoxybenzaldehyde. Through research, I have a further understanding and discovery of 123-11-5

In order to prepare bridging chiral p-tert-butylcalix[4]crown-5 with a mononitro bridge substituent in a 1,3-alternate conformation, a mononitration method of calix[4]arene bridging methylene has been first developed with tert-butyl nitrite as a nitration reagent. The effects of solvent, reaction temperature, reaction time, and nitration reagent dosage on bridge mononitration have been deeply explored to obtain an optimal nitration condition. The facile nitration presents a new key for calix[4]arene bridge derivatization. After further modification and diastereoisomeric resolution, a pair of bridging chiral p-tert-butylcalix[4]arenes with a monoamino bridge substituent were produced from the bridge-mono-nitrated calix[4]arene. Their preliminary catalysis results in the Henry reaction show good catalytic activities (up to 95% yield) and still low but obviously enhanced enantioselectivities (up to 22.3% ee from 7a, 6% ee from 1), which confirms that the structural transformation indeed improves asymmetric catalysis performances of bridging chiral calix[4]crown-5 amines in a 1,3-alternate conformation.

Application In Synthesis of 4-Methoxybenzaldehyde. About 4-Methoxybenzaldehyde, If you have any questions, you can contact Peng, XB; He, D; Sun, GN; Yu, Y; Ma, YH; Tang, SA; Dong, WL; Li, SY or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Product Details of 100-51-6. Nath, I; Chakraborty, J; Zhang, GK; Chen, C; Chaemchuen, S; Park, J; Zhuiykov, S; Han, T; Verpoort, F in [Nath, Ipsita; Chakraborty, Jeet; Chen, Cheng; Chaemchuen, Somboon; Verpoort, Francis] Wuhan Univ Technol, Lab Organometall Catalysis & Ordered Mat, State Key Lab Adv Technol Mat Synth & Proc, Wuhan 430070, Peoples R China; [Nath, Ipsita; Chakraborty, Jeet; Zhang, Gaoke] Wuhan Univ Technol, Sch Resources & Environm Engn, Wuhan 430070, Peoples R China; [Chaemchuen, Somboon; Verpoort, Francis] Natl Res Tomsk Polytech Univ, Lenin Ave 30, Tomsk 634050, Russia; [Park, Jihae; Zhuiykov, Serge; Han, Taejun; Verpoort, Francis] Univ Ghent, Global Campus,119 Songdomunhwa Ro, Incheon 406840, South Korea published Understanding the roles of variable Pd(II)/Pd(0) ratio supported on conjugated poly-azobenzene network: From characteristic alteration in properties to their cooperation towards visible-light-induced selective hydrogenation in 2020.0, Cited 51.0. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6.

Selective hydrogenation of organic functionalities at environmentally benign conditions using visible light is of great industrial and economic significance. Herein we report visible-light-induced rapid, almost quantitative and selective hydrogenation of olefins to respective mono-reduced products using cooperative performance of Pd(0) nanoparticles (NPs) and Pd(II) ions evenly distributed on a newly synthesized conjugated mesoporous poly-azobenzene network. Role of variable Pd(0)/Pd(II) ratio on the properties of polymeric networks and their overall catalytic abilities is critically investigated. This is the first proposed example of cooperative hydrogenation by simultaneous activation of H-2 and unsaturated substrates using Mott-Schottky heterojunction between Pd NPs and the semiconducting polymer, with the help of Pd(II)-site-mediated eta-coordination. A control over selective mono-reduction of diene with identical double bonds was also obtained. The catalytic activity retained for other non-olefinic functionalities as well. (C) 2020 Elsevier Inc. All rights reserved.

Product Details of 100-51-6. About Benzyl Alcohol, If you have any questions, you can contact Nath, I; Chakraborty, J; Zhang, GK; Chen, C; Chaemchuen, S; Park, J; Zhuiykov, S; Han, T; Verpoort, F or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles