An article Catalytic Asymmetric Intermolecular Radical Aminotrifluoromethylation of Alkenes with Hydrazines by Cu(I)/CPA Cooperative Catalysis WOS:000573846600001 published article about UNACTIVATED ALKENES; INTRAMOLECULAR AMINOTRIFLUOROMETHYLATION; TRIFLUOROMETHYLATION; OLEFINS; AMINOPERFLUOROALKYLATION; AMINODIFLUOROMETHYLATION; DIFUNCTIONALIZATION; FUNCTIONALIZATION; FLUORINATION in [Wang, Zhe; Shi, Zhichao; Zhan, Feng; Lin, Jin-Shun] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China; [Wang, Zhe; Shi, Zhichao; Zhan, Feng; Lin, Jin-Shun; Jiang, Yuyang] Tsinghua Shenzhen Int Grad Sch, State Key Lab Chem Oncogen, Key Lab Chem Biol, Shenzhen 518055, Peoples R China; [Cheng, Jiang-Tao; Wang, Na; Jiang, Sheng-Peng; Liu, Xin-Yuan] Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen 518055, Peoples R China; [Cheng, Jiang-Tao; Wang, Na; Jiang, Sheng-Peng; Liu, Xin-Yuan] Southern Univ Sci & Technol, Dept Chem, Guangdong Prov Key Lab Catalysis, Shenzhen 518055, Peoples R China; [Jiang, Yuyang] Tsinghua Univ, Sch Pharmaceut Sci, Beijing 100084, Peoples R China in 2021.0, Cited 77.0. The Name is 4′-Hydroxyacetophenone. Through research, I have a further understanding and discovery of 99-93-4. Name: 4′-Hydroxyacetophenone
A first catalytic enantioselective intermolecular radical aminotrifluoromethylation of alkene with hydrazine and Togni’s reagent by Cu(I)/CPA cooperative catalysis has been reported, accessing diversely substituted CF3-containing enantioenriched diarylmethylamines bearing an alpha-tertiary stereocenter with high enantioselectivity and excellent chemoselectivity. The highly asymmetric induction of C-N bond formation between hydrazine and the carbocation intermediate was achieved by using a CPA catalystviahydrogen-bonding and ion pair interaction.
Name: 4′-Hydroxyacetophenone. About 4′-Hydroxyacetophenone, If you have any questions, you can contact Wang, Z; Cheng, JT; Shi, ZC; Wang, N; Zhan, F; Jiang, SP; Lin, JS; Jiang, YY; Liu, XY or concate me.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles