An article Rare-earth metal complexes derived from the acids Ph2C(X)CO2H (X=OH, NH2): Structural and ring opening polymerization (ROP) studies WOS:000598092500008 published article about SOLVENT-FREE CONDITIONS; SCHIFF-BASE LIGANDS; CHALLENGES; CATALYSIS; LACTIDES; IMIDO; OH in [Collins, Jack; Santoro, Orlando; Prior, Timothy J.; Redshaw, Carl] Univ Hull, Dept Chem & Biochem, Cottingham Rd, Kingston Upon Hull HU6 7RX, N Humberside, England; [Chen, Kai] Nanjing Univ Informat Sci & Technol, Sch Environm Sci & Engn, Jiangsu Key Lab Atmospher Environm Monitoring & P, Collaborat Innovat Ctr Atmospher Environm & Equip, Nanjing 210044, Peoples R China in 2021.0, Cited 44.0. Product Details of 100-51-6. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6
Treatment of Ln(NO3)(3)center dot 6H(2)O (Ln = La, Ce) with an equimolar amount of 2,2′-diphenylglycine (DpgH) in ethanol afforded the corresponding hexacoordinated complexes (DpgH(+/-))(3)Ln(NO3)(3)center dot H2O (DpgH(+/-) = zwitterionic 2,2′-diphenylglycine, Ln = La (1), Ce (2)). The spectroscopic and structural features of these compounds have been investigated. Similar reactions with the related benzilic acid (BenzH(2)) were unsuccessful. The catalytic behaviour of 1 and 2 in the homo- and copolymerization of epsilon-caprolactone (epsilon-CL) and rac-lactide (r-LA) has been investigated herein. In the case of epsilon-CL, the two complexes exhibited comparable activity, allowing for complete monomer conversion under aerobic and solvent-free conditions at 150 degrees C in 24 h. With respect to the ROP of r-LA, 1 was found to be completely inactive, while only 8% conversion was achieved in the presence of 2. Liquid oligomers were isolated during epsilon-CL/r-LA copolymerization in the presence of both complexes. The catalytic activity of the pre-ligands DpgH and BenzH(2) (i.e. metal-free) was also examined. Interestingly, only BenzH(2) was found to be active, although it required a higher catalyst loading and the presence of benzyl alcohol as co-activator. (C) 2020 Elsevier B.V. All rights reserved.
Product Details of 100-51-6. About Benzyl Alcohol, If you have any questions, you can contact Collins, J; Santoro, O; Prior, TJ; Chen, K; Redshaw, C or concate me.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles