Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 1008-89-5, is researched, SMILESS is C1(C2=CC=CC=C2)=NC=CC=C1, Molecular C11H9NJournal, Article, Chemistry – A European Journal called Rhoda-Electrocatalyzed C-H Methylation and Paired Electrocatalyzed C-H Ethylation and Propylation, Author is Kucinski, Krzysztof; Simon, Hendrik; Ackermann, Lutz, the main research direction is nitroheteroarene potassium alkyltrifluoroborate rhodium electrocatalyst regioselective alkylation green chem; alkyl nitroheteroarene preparation; C−H activation; electrochemistry; methylation; paired electrolysis; rhodium.Product Details of 1008-89-5.
Herein, the rhoda-electrocatalyzed C-H activation/alkylation of several N-heteroarenes was described. This catalytic approach was successfully applied to several arenes, including biol. relevant purines, diazepam, and amino acids. The versatile C-H alkylation featured water as a co-solvent and user-friendly trifluoroborates as alkylating agents. Finally, the rhoda-electrocatalysis with unsaturated organotrifluoroborates proceeded by paired electrolysis.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles