Authors Kumar, A; Thallada, B in ROYAL SOC CHEMISTRY published article about FUEL-RANGE HYDROCARBONS; SELECTIVE HYDRODEOXYGENATION; PHASE HYDRODEOXYGENATION; AQUEOUS-PHASE; REACTION PATHWAYS; EFFICIENT; GUAIACOL; RU; HYDROGENATION; CYCLOHEXANOL in [Kumar, Adarsh; Thallada, Bhaskar] CSIR Indian Inst Petr IIP, Thermocatalyt Proc Area TPA, Mat Resource Efficiency Div MRED, Dehra Dun 248005, Uttarakhand, India; [Kumar, Adarsh; Thallada, Bhaskar] Acad Sci & Innovat Res AcSIR, Ghaziabad, Uttar Pradesh, India in 2021.0, Cited 61.0. Application In Synthesis of Mequinol. The Name is Mequinol. Through research, I have a further understanding and discovery of 150-76-5
The synthesis of efficient and engineered noble metal catalysts for selective conversion of waste renewable lignin to valuable chemical building blocks is crucial for the economic viability of current biorefineries. Motivated by the water effect in promoting catalytic activity, hydrous ruthenium oxide (HRO) incorporating acidic systems (H-ZSM5, HY zeolite, gamma-Al2O3, and SiO2) were investigated for selective hydrodeoxygenation of lignin-derived phenols in the aqueous phase. The results indicated that the hydrous form (surface bonded water molecules) of ruthenium and high acidity of the support promote the hydrogenolysis activity of the as-prepared catalysts and increase the yield of alkylated cyclohexanols. Among all catalysts, HRO@Y showed the best performance and afforded the highest selectivity to cyclohexanols. Intensive catalyst characterization demonstrated that in situ metal formation, a large number of acid sites, good metal dispersion, and high adsorption capacity of HRO@Y for polar fractions were responsible for the efficient activity. Water considerably improved the selective hydrodeoxygenation activity of the catalyst by promoting hydrogenation and demethoxylation and hindering dehydration.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles