COA of Formula: C9H10O3. Recently I am researching about CONJUGATED DIENES; ENANTIOSELECTIVE 1,2-DIFUNCTIONALIZATION; INTERMOLECULAR 1,2-DIAMINATION; REGIOSELECTIVE DIAMINATION; PALLADIUM; ALKENES; OLEFINS; ALKYL; ISOTHIOCYANATES; CHEMISTRY, Saw an article supported by the EPFL (Switzerland); Swiss National Science FoundationSwiss National Science Foundation (SNSF)European Commission [SNSF 200021-178846/1]; China Scholarship CouncilChina Scholarship Council. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Guo, WS; Wang, Q; Zhu, JP. The CAS is 120-14-9. Through research, I have a further understanding and discovery of 3,4-Dimethoxybenzaldehyde
Selective three-component 1,2-diamination of 1,3-dienes with concurrent introduction of two orthogonally protected amino groups remains unknown despite its significant synthetic potential. We report herein that reaction of conjugated dienes with N-aminopyridinium salts and TMSNCS affords 1,2-aminoisothiocyanation products in a highly chemo- and regio-selective manner under mild photoredox catalytic conditions. Mechanistic studies indicate that the facile isomerization of allyl thiocyanates to allyl isothiocyanates under photocatalytic conditions is responsible for the selective formation of the observed products. The mild isomerization protocol is expected to find applications in the synthesis of allyl isothiocyanates in a broad sense.
COA of Formula: C9H10O3. About 3,4-Dimethoxybenzaldehyde, If you have any questions, you can contact Guo, WS; Wang, Q; Zhu, JP or concate me.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles