An article Samarium-based Grignard-type addition of organohalides to carbonyl compounds under catalysis of CuI WOS:000655651300001 published article about CROSS-COUPLING REACTIONS; CHEMOSELECTIVE REDUCTION; BARBIER REACTION; METAL; REAGENTS; HALIDES; ALDEHYDES; COPPER in [Xiao, Shuhuan; Liu, Chen; Song, Bin; Qi, Yan; Liu, Yongjun] Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Key Lab Opt Elect Sensing & Analyt Chem Life Sci, Qingdao 266042, Peoples R China; [Wang, Liang] Qingdao Agr Univ, Coll Chem & Pharmaceut Sci, Changcheng Rd 700, Qingdao 266109, Peoples R China in 2021, Cited 59. The Name is 4-Methoxybenzaldehyde. Through research, I have a further understanding and discovery of 123-11-5. Formula: C8H8O2
Grignard-type additions were readily achieved under the mediation of CuI (10 mol%) and samarium (2 equiv.) by employing various organohalides, e.g. benzyl, aryl, heterocyclic and aliphatic halides (Cl, Br or I), and diverse carbonyl compounds (e.g. carbonic esters, carboxylic esters, acid anhydrides, acyl chlorides, ketones, aldehydes, propylene epoxides and formamides) to afford alcohols, ketones and aldehydes, respectively, with high efficiency and chemoselectivity, in which the organosamarium intermediate might be involved.
Formula: C8H8O2. Welcome to talk about 123-11-5, If you have any questions, you can contact Xiao, SH; Liu, C; Song, B; Wang, L; Qi, Y; Liu, YJ or send Email.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles