Recently I am researching about SINGLE-ELECTRON TRANSMETALATION; CYCLIZATIONS; AMINATION; ALCOHOLS; HALIDES; KETONES; DIENES, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21772208, 21702212, 21633013]; Natural Science Foundation of Jiangsu ProvinceNatural Science Foundation of Jiangsu Province [BK20201183]; Key Research Program of Frontier Sciences of CAS [QYZDJSSW-SLH051]. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Li, YL; Zhang, SQ; Chen, J; Xia, JB. The CAS is 123-11-5. Through research, I have a further understanding and discovery of 4-Methoxybenzaldehyde. Recommanded Product: 123-11-5
A Co-catalyzed highly regio- and enantioselective reductive coupling of alkynes and aldehydes has been developed under visible light photoredox dual catalysis. A variety of enantioenriched allylic alcohols have been obtained by using unsymmetrical internal alkynes and commercially available catalyst, chiral ligand, and reagents. It is noteworthy that this approach has considerable advantages, such as excellent regio- (>95:5 for >40 examples), stereo- (up to >95:5 E/Z), and enantioselectivity (92-99% ee, >35 examples) control, mild reaction conditions, broad substrate scope, and good functional group compatibility, making it a great improvement to enantioselective alkyne-aldehyde reductive coupling reactions.
Recommanded Product: 123-11-5. About 4-Methoxybenzaldehyde, If you have any questions, you can contact Li, YL; Zhang, SQ; Chen, J; Xia, JB or concate me.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles