An article Triruthenium carbonyl complexes containing bidentate pyridine-alkoxide ligands for highly efficient oxidation of primary and secondary alcohols WOS:000496326100001 published article about CATALYZED AEROBIC OXIDATION; SELECTIVE OXIDATION; DEHYDROGENATION; NANOPARTICLES in [Yue, Xiaohui; Yan, Xinlong; Huo, Shuaicong; Dong, Qing; Zhang, Junhua; Hao, Zhiqiang; Han, Zhangang; Lin, Jin] Hebei Normal Univ, Coll Chem & Mat Sci, Natl Demonstrat Ctr Expt Chem Educ, Hebei Key Lab Organ Funct Mol, Shijiazhuang 050024, Hebei, Peoples R China in 2020.0, Cited 44.0. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6. Computed Properties of C7H8O
Reactions of substituted pyridylalkanol 6-CH3PyCH2CH(OH)R (R = Ph ((LH)-H-1), R = 4-CH3C6H4 ((LH)-H-2), R = 4-OCH3C6H4 ((LH)-H-3), R = 4-ClC6H4 ((LH)-H-4), R = 4-BrC6H4 ((LH)-H-5), R = 4-CF3C6H4 ((LH)-H-6)) with Ru-3(CO)(12) in refluxing tetrahydrofuran afforded the corresponding ruthenium carbonyl complexes [6-CH3PyCH2CHRO](2)Ru-3(CO)(8) (R = Ph (1a), R = 4-CH3C6H4 (1b), R = 4-OCH3C6H4 (1c), R = 4-ClC6H4 (1d), R = 4-BrC6H4 (1e), R = 4-CF3C6H4 (1f)) in good yields. These ruthenium complexes were well characterized using elemental analysis and Fourier transform infrared and NMR spectroscopies. Furthermore, their crystal structures were determined using single-crystal X-ray diffraction analysis. Complexes 1a-1f were found to be highly active toward oxidation of a wide range of primary and secondary alcohols to corresponding aldehydes and ketones within 5 minutes in the presence of N-methylmorpholine-N-oxide as oxidant.
Computed Properties of C7H8O. About Benzyl Alcohol, If you have any questions, you can contact Yue, XH; Yan, XL; Huo, SC; Dong, Q; Zhang, JH; Hao, ZQ; Han, ZG; Lin, J or concate me.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles