Name: m-Methoxyphenol. I found the field of Chemistry very interesting. Saw the article Enantioselective Synthesis of Tertiary alpha,alpha-Diaryl Carbonyl Compounds Using Chiral N,N ‘-Dioxides under Umpolung Conditions published in 2020.0, Reprint Addresses Shin, S (corresponding author), Hanyang Univ, Dept Chem, Res Inst Nat Sci, Seoul 04763, South Korea.; Shin, S (corresponding author), Hanyang Univ, Ctr New Direct Organ Synth CNOS, Seoul 04763, South Korea.. The CAS is 150-19-6. Through research, I have a further understanding and discovery of m-Methoxyphenol.
Bronsted acid-catalyzed addition of the chiral N,N’-dioxide into ynamides generated enolonium ions in situ which underwent enantioselective alkylation by indoles, pyrroles, and phenols, without racemization of the formed tertiary center. This external oxidant approach allows for the use of unmodified nucleophiles and does not leave trace groups from the oxidant, which significantly increases the synthetic efficiency and the product diversity. Furthermore, the byproduct of the N,N’-dioxide could be efficiently recycled into an optically pure form.
Name: m-Methoxyphenol. About m-Methoxyphenol, If you have any questions, you can contact Urn, TW; Lee, G; Shin, S or concate me.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles