Authors Chang, XH; Zhang, QL; Guo, C in AMER CHEMICAL SOC published article about H FUNCTIONALIZATION; OXIDATIVE AMINATION; ELECTRON-TRANSFER; AMIDYL RADICALS; METAL; GENERATION; CLEAVAGE; ETHERS; ELECTROSYNTHESIS; HETEROARENES in [Chang, Xihao; Zhang, Qinglin; Guo, Chang] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China in 2019, Cited 77. Product Details of 98-17-9. The Name is 3-(Trifluoromethyl)phenol. Through research, I have a further understanding and discovery of 98-17-9
A conceptually new and synthetically valuable radical Smiles rearrangement reaction is reported under undivided electrolytic conditions. This protocol employs an entirely new strategy for the electrochemical radical Smiles rearrangement. Remarkably, an amidyl radical generated from the cleavage of the N-O bond under reductive electrolytic conditions plays a crucial role in this transformation. Various hydroxylamine derivatives bearing different substituents are suitable in this electrochemical transformation, furnishing the corresponding amides in up to 86% yield.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles