SDS of cas: 98-17-9. Recently I am researching about C-H BOND; TERMINAL ALKYNES; COPPER; PALLADIUM; HALIDES; ALKENES; ESTERS; IODINATION; COMPLEXES; PHENOLS, Saw an article supported by the Research Funds for the Central Universities [XDJK2017B015, XDJK2018C040]; Doctoral Fund of Southwest UniversitySouthwest University – China [SWU111075, SWU117056]; Beijing National Laboratory of Molecular Sciences (BNLMS) [20140130]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21672173]. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Wu, YB; Xiao, L; Mao, CL; Zang, ZL; Zhou, CH; Cai, GX. The CAS is 98-17-9. Through research, I have a further understanding and discovery of 3-(Trifluoromethyl)phenol
An approach to preparing enynyl-aryl ethers from phenols and phenylacetylenes is described. This method without extra ligands, overcoming the favored Glaser-Hay dimerization of alkyne, features a wide substrate scope (38 examples including endofolliculina and indole) and the merits of high atom and step economy, good regio- and stereoselectivity (Z-isomers major) in moderate to good isolated yields. Mechanistic studies show that the reaction is enabled by distinctive copper/iodide tandem catalysis.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles