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Recommanded Product: 100-51-6. About Benzyl Alcohol, If you have any questions, you can contact Cattaneo, S; Capelli, S; Stucchi, M; Bossola, F; Dal Santo, V; Araujo-Lopez, E; Sharapa, DI; Studt, F; Villa, A; Chieregato, A; Vandegehuchte, BD; Prati, L or concate me.

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In this manuscript, we investigated in detail one of the critical parameters that govern the reactivity of the carbonylic group toward hydrogenation and hydrodeoxygenation: the effect of the side chains of aldehydes. We observed that the presence of a pi-electron conjugation on the side chains strongly affects the conversion of aldehydes to alcohols and hydrocarbons under the reaction conditions studied. In particular, the presence of a strong pi-electron conjugation, such as the aromatic ring, enables the hydrogenation and further hydrodeoxygenation of the carbonylic group, while, on the other hand, molecules with no or weak pi-electron conjugation (such as alkyl chains or single conjugated C = C double bonds) remained inactive. These results were supported by adsorption analyses as well as theoretical models, which showed that differences in adsorption mode and strength between two model substrates (benzaldehyde and octanal) were not the decisive factors in the conversion of the carbonyl group. (C) 2021 Elsevier Inc. All rights reserved.

Recommanded Product: 100-51-6. About Benzyl Alcohol, If you have any questions, you can contact Cattaneo, S; Capelli, S; Stucchi, M; Bossola, F; Dal Santo, V; Araujo-Lopez, E; Sharapa, DI; Studt, F; Villa, A; Chieregato, A; Vandegehuchte, BD; Prati, L or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles