Authors Zhao, FQ; Ai, HJ; Wu, XF in WILEY-V C H VERLAG GMBH published article about in [Zhao, Fengqian; Ai, Han-Jun; Wu, Xiao-Feng] Univ Rostock, Leibniz Inst Katalyse EV, Albert Einstein Str 29a, D-18059 Rostock, Germany; [Wu, Xiao-Feng] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China in 2021.0, Cited 11.0. Category: indole-building-block. The Name is Mequinol. Through research, I have a further understanding and discovery of 150-76-5
Main observation and conclusion High CO pressure (> 40 bar) is usually needed in radical carbonylation reactions in the absence of metal catalyst. In this communication, we developed a transition-metal-free radical carbonylation of activated alkylamines with phenols and alcohols under low CO pressure (1-6 bar). Various esters were obtained in moderate to excellent yields under simple reaction conditions with good functional group compatibility.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles