COA of Formula: C7H8O. Lu, SY; Wang, K in [Lu, Shiyao; Wang, Kai] Tsinghua Univ, Dept Chem Engn, State Key Lab Chem Engn, Beijing 100084, Peoples R China published Kinetic study of TBD catalyzed delta-valerolactone polymerization using a gas-driven droplet flow reactor in 2019, Cited 41. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6.
The kinetics of aliphatic polyester synthesis is critical to understanding the mechanism of ring-opening polymerization and making the reaction more controllable. In this paper, we introduce a gas-driven droplet flow reactor to determine the reaction kinetics of 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) catalyzed delta-valerolactone polymerization. Only 2 mL reaction solution was used for each test, which significantly reduced the work in preparing the anhydrous reactants. The experimental results indicated that the orders of the catalyst and the alcohol in the kinetic model are close to 1 and 0, respectively, and therefore the rate-determining step was the activation reaction between the monomer and catalyst. Then, the activated monomer quickly reacts with the end hydroxyl in the polymer chain to finish the reaction. In the end, we calculated the activation energy of the rate-determining reaction, which is only 7.302 +/- 0.047 kJ mol(-1).
COA of Formula: C7H8O. Welcome to talk about 100-51-6, If you have any questions, you can contact Lu, SY; Wang, K or send Email.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles