Product Details of 100-51-6. In 2020 CHEM-ASIAN J published article about HYDROGEN-ATOM TRANSFER; METAL-OXO COMPLEXES; C-H OXIDATION; ELECTRON-TRANSFER; LIGANDS; DIHYDROXYLATION; IRON(IV)-OXO; IMPACT; WATER in [Dutta, Manali; Bania, Kusum K.; Pratihar, Sanjay] Tezpur Univ, Dept Chem Sci, Napaam 784028, Assam, India; [Pratihar, Sanjay] CSIR, Cent Salt & Marine Chem Res Inst, Inorgan Mat & Catalysis Div, GB Marg, Bhavnagar 364002, Gujarat, India in 2020, Cited 38. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6.
Herein we disclosed the use of a remote ‘imidazole’-based precatalyst [(para-cymene)Ru-II(L)Cl](+), C-1 where L=2-(4-substituted-phenyl)-1H-imidazo[4,5-f]([1,10]) phenanthroline) for the selective oxidation of a variety of alkyl arenes/heteroarenes and alcohols to their corresponding aldehydes or ketones in presence of tert-butyl hydroperoxide (TBHP). The remote ‘imidazole’ moiety present in the complex facilitates the activation of oxidant and subsequent generation of active species via the release of para-cymene from C-1, which in-turn was less effective without the ‘imidazole’ moiety. The mechanistic features of C-1 promoted oxidation of alkyl arenes were also assessed from spectroscopic, kinetic, and few control experiments. The substrate scope for C-1 promoted oxidation reaction was assessed based on the selective oxidation of 27-different alkyl arenes/heteroarenes and 25 different alcohols to their corresponding aldehydes/ketones in moderate to good yields.
Product Details of 100-51-6. About Benzyl Alcohol, If you have any questions, you can contact Dutta, M; Bania, KK; Pratihar, S or concate me.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles