An article Selective Activation of Benzyl Alcohol Coupled with Photoelectrochemical Water Oxidation via a Radical Relay Strategy WOS:000530090800008 published article about LAYERED DOUBLE HYDROXIDE; C-H BONDS; TIO2 PHOTOCATALYSTS; AROMATIC ALCOHOLS; AEROBIC OXIDATION; MOLECULAR-OXYGEN; EFFICIENT; MECHANISM; BENZENE; GENERATION in [Luo, Lan; Wang, Zhou-jun; Xiang, Xu] Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China; [Yan, Dongpeng] Beijing Normal Univ, Coll Chem, Minist Educ, Key Lab Theoret & Computat Photochem, Beijing 100875, Peoples R China; [Ye, Jinhua] Natl Inst Mat Sci NIMS, Int Ctr Mat Nanoarchitecton WPI MANA, Tsukuba, Ibaraki 3050044, Japan; [Ye, Jinhua] Tianjin Univ, TJU NIMS Int Collaborat Lab, Sch Mat Sci & Engn, Tianjin 300072, Peoples R China; [Ye, Jinhua] Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300072, Peoples R China in 2020.0, Cited 57.0. Name: Benzyl Alcohol. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6
Selective oxidation to produce target chemicals usually need activation of O-2 at high temperature and/or pressure, which have largely restricted its practical operation and application. Here, we put forward a radical relay strategy coupling photoelectrochemical (PEC) water oxidation toward efficiently selective conversion of benzyl alcohol (BA) to benzaldehyde (BAD). An illuminated BiVO4 (BVO) photoanode covered with an ultrathin (similar to 3 nm) hydrothermally synthesized layered double hydroxide (U-LDH) catalyst and graphene (G) exhibited >99% selectivity to BAD (1.2 V vs. RHE). Mechanistic studies and DFT calculation verified that the hydroxyl radicals (center dot OH) generated from the oxidation of water are bound to the surface of U-LDH through hydrogen-bonding interactions and the energy is lowered. Fourier transform infrared spectroscopy showed that BA is adsorbed to the U-LDH catalyst, but BAD is not. Thus, the selectivity is favored not only by the controlled oxidation capacity of center dot OH radicals but the desorption of the desired product from the catalyst before further oxidation occurs. This work introduces an alternative PEC way to achieve mild and selective oxidation of BA derivatives based on ternary G@U-LDH@BVO catalysts.
About Benzyl Alcohol, If you have any questions, you can contact Luo, L; Wang, ZJ; Xiang, X; Yan, DP; Ye, JH or concate me.. Name: Benzyl Alcohol
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,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles